Physical and chemical study of manganese dioxide sorbent after sorption of lithium from brines
DOI:
https://doi.org/10.31643/2025/6445.28Keywords:
lithium, brine, sorbent, manganese dioxide, sorption, exchange capacity.Abstract
The article presents the results of the study for the synthesized manganese dioxide sorbent after its saturation with lithium from brine. The sorbent was previously prepared. For this purpose the mixture of manganese oxide compounds was kept with lithium hydroxide in a wet state at 125 °C, calcinated at 450 °C and then the precursor was treated with dilute hydrochloric acid. The process intended to saturate the sorbent with lithium was performed by putting it in contact with a lithium-containing brine with a pH of 8.77 at T = 40°C for 24 hours in four cycles. The sorbent after saturation was studied using X-ray phase and thermal analysis methods. X-ray phase analysis showed that lithium-containing phases are represented by such compounds as Li(Li0.17Mn0.83)2O4 and Li0.78Mn1.88O4. The results of thermal analysis show the possibility of phases to be in the sorbent after saturation LiMn2O4 and Li1,3Mn2O4 phases. The study results showed that ion-exchange interaction takes place between the lithium-ion from the brine and the proton from the manganese-oxide spinel composition to a greater extent during sorption. Besides, the redox nature of the interaction is present during the sorption of lithium. All lithium intercalation reactions proceed topotactically without significant changes in the main structure of the original sorbent.
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Rowan TH, Andrew H, Frances W, Evi P, Robert Pl, Jordan JL. Life cycle assessment and water use impacts of lithium production from salar deposits: Challenges and opportunities. Resources, Conservation and Recycling. 2024; 207:107554. https://doi.org/10.1016/j.resconrec.2024.107554
Weishang J, Jingfang Zh, Luojia Zh, Hao Zh, Wei Z, Liping W. Lithium-rich alloy as stable lithium metal composite anode for lithium batteries. eScience. 2024, 100266. https://doi.org/10.1016/j.esci.2024.100266
Friedlingstein P, et al. Global Carbon Budget 2022. Earth System Science Data. 2022; 14(11):4811-4900. https://doi.org/10.5194/essd-14-4811-2022
The National Energy Report Kazenergy 2023. Kazakhstan Association of Oil, Gaz and Energy Sector Organizations, Kazenergy. https://www.kazenergy.com/en/operation/ned/2177/,2023
The United Nations Framework Convention On Climate Change, https://unfccc.int/process-and-meetings/what-is-the-united-nations-framework-convention-on-climate-change
Environmental Protection Agency. Overview of Greenhouses gases. https://www.epa.gov/ghgemissions/overview-greenhouse-gases
Shukla PR, Skea J, Slade R, Fradera R, Pathak M, Alaa AK, Malek B, Renee VD, Hasija A, et al. Climate Change 2022 Mitigation of Climate Change Working Group III Contribution to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change. Cambridge: Cambridge University Press. 2022.
Yang J, Xia B, Shang Y, Huang W, Mi C. Improved Battery Parameter Estimation Method Considering Operating Scenarios for HEV/EV Applications. Energies. 2017; 10(1):5. https://doi.org/10.3390/en10010005
Stroe DI, Swierczynski M, Stroe AI, Knudsen KS. Generalized Characterization Methodology for Performance Modelling of Lithium-Ion Batteries. Batteries. 2016; 2(4):37. https://doi.org/10.3390/batteries2040037
Chen Z, Li X, Shen J, Yan W, Xiao R. A Novel State of Charge Estimation Algorithm for Lithium-Ion Battery Packs of Electric Vehicles. Energies. 2016; 9(9):710. https://doi.org/10.3390/en9090710
Gao J, Zhang Y, He H. A Real-Time Joint Estimator for Model Parameters and State of Charge of Lithium-Ion Batteries in Electric Vehicles. Energies. 2015; 8(8):8594-8612. https://doi.org/10.3390/en8088594
Bharathidasan M, Indragandhi V, Vishnu S, Michał J, Zbigniew L. A review on electric vehicle: Technologies, energy trading, and cyber security. Energy Reports. 2022; 8:9662-9685. https://doi.org/10.1016/j.egyr.2022.07.145
Marcinov V, Klimko J, Takacova Z, Piroskova J, Miskufova A, Sommerfeld M, Dertmann C, Friedrich B, Orac D. Lithium Production and Recovery Methods: Overview of Lithium Losses. Metals. 2023; 13(7):1213. https://doi.org/10.3390/met13071213
Battery 2030: Resilient, sustainable and circular. https://www.mckinsey.com/industries/automotive-and-assembly/our-insights/battery-2030-resilient-sustainable-and-circular#/
Kenzhaliyev B, Surkova T, Berkinbayeva A, Amanzholova L, Mishra B, Abdikerim B, Yessimova D. Modification of Natural Minerals with Technogenic Raw Materials. Metals. 2022; 12:1907. https://doi.org/10.3390/met12111907
Basudev S. Recovery and recycling of lithium: A review. Separation and Purification Technology. 2017; 172:388-403. https://doi.org/10.1016/j.seppur.2016.08.031
Garcia LV, Ho YC, Myo Thant MM, Han DS, Lim JW. Lithium in a Sustainable Circular Economy: A Comprehensive Review. Processes. 2023; 11(2):418. https://doi.org/10.3390/pr11020418
Mahran GMA, Gado MA, Fathy WM, ElDeeb AB. Eco-Friendly Recycling of Lithium Batteries for Extraction of High-Purity Metals. Materials. 2023; 16:4662. https://doi.org/10.3390/ma16134662
Stopic S, Friedrich B. Advances in Understanding of the Application of Unit Operations in Metallurgy of Rare Earth Elements. Metals. 2021; 11:978. https://doi.org/10.3390/met11060978
Meng F, McNeice J, Zadeh SS, Ghahreman A. Review of Lihium Production and Recovery from Minerals, Brines, and Lithium-Ion Batteries. Mineral Processing and Extractive Metallurgy Review. 2021; 42(2):123-141. https://doi.org/10.1080/08827508.2019.1668387
Ye Zh, Yuehua H, Li W, Wei S. Systematic review of lithium extraction from salt-lake brines via precipitation approaches. Minerals Engineering. 2019; 139:105868. https://doi.org/10.1016/j.mineng.2019.105868
Xianhui L, Yinghui M, Weihua Q, Senlin Sh, Chuyang YT, Jianxin L. Membrane-based technologies for lithium recovery from water lithium resources: A review. Journal of Membrane Science. 2019; 591:117317. https://doi.org/10.1016/j.memsci.2019.117317
Ziller S, Von Bulow JF, Dahl SL. A fast sol - gel synthesis leading to highly crystalline birnessites under non-hydrothermal conditions. Dalton Transactions/ 2017; 46(14):4582-4588. https://doi:10.1039/c7dt00109f
Xiaorong M, Yue J, Jiaming L, Zhengmeng S, Zhenpeng W. Electrochemical recovery of lithium from brine by highly stable truncated octahedral LiNi0.05Mn1.95O4. Chemical Engineering Science. 2024; 283:119400. https://doi.org/10.1016/j.ces.2023.119400
Tangkas IWCWH, Sujoto VSH, Astuti W. et al. Synthesis of Titanium Ion Sieves and Its Application for Lithium Recovery from Artificial Indonesian Geothermal Brine. J. Sustain. Metall. 2023; 9:613-624. https://doi.org/10.1007/s40831-023-00664-7
Pratima M, Pandey BD, Mankhand TR. Extraction of lithium from primary and secondary sources by pre-treatment, leaching and separation: A comprehensive review. Hydrometallurgy. 2014; 150:192-208. https://doi.org/10.1016/j.hydromet.2014.10.012
Adam S, Salman S, David M, Alan VC, Silvia R, Carmen AV, José MC, Daniel SA. Lithium recovery from hydraulic fracturing flowback and produced water using a selective ion exchange sorbent. Chemical Engineering Journal. 2021; 426:1385-8947. https://doi.org/10.1016/j.cej.2021.13071
Qian Ch, Zhijie Ch, Hongqiang L, Bing-Jie N. Advanced lithium ion-sieves for sustainable lithium recovery from brines. Sustainable Horizons. 2024; 9:100093. https://doi.org/10.1016/j.horiz.2024.100093
Yasin O, Zahra N, Mahmoud N, Nasrin Sh, Morteza A, Khatereh P, Amir R. Recent advances in nanomaterial development for lithium ion-sieving technologies. Desalination 2022; 529:115624. https://doi.org/10.1016/j.desal.2022.115624
Shulei W, Xin Ch, Ying Zh, Yang Zh, Shili Zh. Lithium adsorption from brine by iron-doped titanium lithium ion sieves. Particuology. 2018; 41:40-47. https://doi.org/10.1016/j.partic.2018.02.001
Snydacker DHI, Hegde V, Aykol M, Wolverton C, Computational Discovery of Li-M-O Ion Exchange Materials for Lithium Extraction from Brines. Chemistry of Materials. 2018; 30:6961. https://10.1021/acs.chemmater.7b03509
Salman S, Bernd GL, Daniel SA. Metal oxide sorbents for the sustainable recovery of lithium from unconventional resources. Applied Materials Today. 2020; 19:100638. https://doi.org/10.1016/j.apmt.2020.100638
Murphy O, Haji MN. A review of technologies for direct lithium extraction from low Li+ concentration aqueous solutions. Frontiers in Chemical Engineering. 2022; 4. https://doi.org/10.3389/fceng.2022.1008680
Chitrakar R, Kahon H, Miyai Y, and Ooi K. Recovery of Lithium from Seawater Using Manganese Oxide Adsorbent (H1.6Mn1.6O4) Derived from Li1.6Mn1.6O4. 2001; 40:2054-2058.
Ryu T, Haldorai Y, Rengaraj A, Shin J, Hong HJ, Lee GW, Han YK, Huh YS, Chung KS. Recovery of Lithium Ions from Seawater Using a Continuous Flow Adsorption Column Packed with Granulated Chitosan-Lithium Manganese Oxide. Industrial & Engineering Chemistry Research. 2016; 55(26):7218-7225. http://dx.doi.org/10.1021/acs.iecr.6b01632
Sun YS, Xiang L, Xiufeng R, Chunxi H, Yuan Zh, Weiping T. Improved structural stability and adsorption capacity of adsorbent material Li1.6Mn1.6O4 via facile surface fluorination. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2021; 629:127465. https://doi.org/10.1016/j.colsurfa.2021.127465
Popov GV. Sovremennyye metody i sredstva izvlecheniya litiya iz teplonositeley geotermalnykh mestorozhdeniy [Modern methods and means of attracting lithium from coolants of geothermal deposits]. Mining information and analytical bulletin. Scientific and technical journal. 2015; 63:256-260. (in Russ.).
Luofeng L, Hongwei Zh, Yushan Zh, Dongmei C, Xinhua Zh. Lithium extraction from seawater by manganese oxide ion sieve MnO2*0.5H2O. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2015; 468:280-284. https://doi.org/10.1016/j.colsurfa.2014.12.025
Klugman IY. Osobennosti iona litiya [Features of lithium ion]. Questions of applied physics: Interuniversity scientific collection. 2020; 27:71-79. (in Russ.)
Gelfman M, Kovalevich O, Yustratov V. Kolloidnaya khimiya [Colloidal chemistry]. SPb.: Lan. 2010, 336. (in Russ.).
Lukman N, Gita, AS, Diah S, Amien W. Synthesis and Characterization of Lithium Manganese Oxide with Different Ratio of Mole on Lithium Recovery Process from Geothermal Fluid of Lumpur Sidoarjo. J. Mater. Sci. Chem. Eng. 2015; 3:56–62.
Chitrakar R, Kanoh H, Miyai Y, Ooi K. A New Type of Manganese Oxide (MnO2 ∙0.5H2O) Derived from Li1.6Mn1.6O4 and Its Lithium Ion-Sieve Properties. Chem. Mater. 2000; 12:3151-3157.
Hayward M. 2.15 - Soft Chemistry Synthesis of Oxides. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. Comprehensive Inorganic Chemistry II. 2nd.ed. From Elements to Applications. 2013.
Tang W, Kanoh H, Ooi K. Lithium ion extraction from orthorhombic LiMnO2 in ammonium peroxodisulfate solutions. J. Solid State Chem. 1999; 142(1):19-28.
Gummow RJ, Liles DC, Thackeray MM. Lithium extraction from orthorhombic lithium manganese oxide and the phase transformation to spinel. Mat. Res. Bull. 1993; 28:1249-1256.
Chitrakar R, Sakane K, Umeno A, Kasaishi Sh, Takagi N, Ooi K. Synthesis of orthorhombic LiMnO2 by solid-phase reaction under steam atmosphere and a study of its heat and acid- treated phases. Journal of Solid State Chemistry. 2002; 169: 66-74.
Ho YS, McKay G. Pseudo-second order model for sorption processes. Process Biochemistry. 1999; 34:451-465.
Xiao J, Nie X, Sun S, Song X, Li P, Yu J. Lithium ion adsorption-desorption properties on spinel Li4Mn5O12 and pH-dependent ion-exchange model. Adv. Powder Technol. 2015; 26:589-594.
Xin X, Yongmei Ch, Pingyu W, Khaled G, Kaiying W, Ting H, Hertanto A, Maohong F. Extraction of lithium with functionalized lithium ion-sieves. Progress in Materials Science. 2016; 84:276-313.
Hunter JC. Preparation of a New Crystal Form of Manganese Dioxide: λ-MnO2. Journal of Solid State Chemistry. 1981; 3:142-147.
Feng Q, Miyai Y, Kanoh H, Ooi K. Li+ Extraction/Insertion with Spinel-Type Lithium Manganese Oxides. Characterization of Redox-Type and Ion-Exchange-Type Sites. Langmuir. 1992; 8:1861-1867.
Buzanov GA. Fazovyye ravnovesiya s uchastiyem tverdykh rastvorov v sisteme Li-Mn-O. [Phase equilibria involving solid solutions in the Li-Mn-O system]. Moscow: Russion science academy. 2016. (in Russ.).
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Copyright (c) 2024 Abdulvaliyev, R., Karshyga, Z., Yersaiynova, A., Yessengaziyev, A., Orynbayev, B., & Kvyatkovskaya, M.
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