Exponential modeling of Al₂O₃ reduction during activation of Navbahor alkaline-earth bentonite
DOI:
https://doi.org/10.31643/2027/6445.44Keywords:
bentonite, acid, activation, relative area, modelling, exponential decay, coefficient of determination (R²).Abstract
In this study, using mathematical modeling, the change in Al2O3 content as a function of acid concentration during hydrochloric acid activation of alkaline-earth bentonite from the Navbahor deposit is investigated. During the experiment, the HCl concentration varied from 5% to 20%, and the change in Al2O3 content was nonlinear. To describe the experimental data obtained during hydrochloric acid activation of alkaline-earth bentonite from the Navbahor deposit, an exponential decay model was proposed, and its parameters were estimated by regression analysis. The accuracy of this approach is supported by the coefficient of determination (R² = 0.964) and the root mean square error (RMSE = 0.231%), indicating high accuracy and stability. The results obtained show that the decrease in Al₂O₃ content under acid activation conditions exhibits a nonlinear dependence on hydrochloric acid concentration rather than on time, and they enable formulation of a mathematical expression for the quantitative description of the process and for evaluating the effect of concentration.
Downloads
References
Zubair NA, Moawia RM, Nasef MM, et al. A Critical Review on Natural Fibers Modifications by Graft Copolymerization for Wastewater Treatment. J Polym Environ. 2022; 30:1199-1227. https://doi.org/10.1007/s10924-021-02269-1
Boyjanov N, Radjabov M, Serkayev Q, Boyjanov I, & Yaxshimuradov N. Activation and comparison of indicators of bentonite clay of the Navbakhor deposit. E3S Web of Conferences. 2024; 563:02018. https://doi.org/10.1051/e3sconf/202456302018
Haidar Abbas, Sarmad Jaafar Mohammed Alrubaye, Ali Fawzi Al-Hussainy, Basim Mohammed Saadi, Mohannad Abdulrazzaq Gati, Talib Kh. Hussein, Boyjanov Nodirbek Ilxomovich, Nafaa Farhan Muften. Role of Carrageenan and Health Approach for Adsorption of Safranin-T Dye from Aqueous Solution by Using Polymer/CNT Surface. Journal Nanostruct. 2025; 15(4): 1798-1807.
Hussein U A-R, Alalwan D H K, Qabel H A, Abid F M, Hamza H H, Ilxomovich B N, Aljeboree A M, & Alkaim A F. Green synthesis and characterization of guar gum/polyacrylamide/activated carbon hydrogel for efficient methylene blue removal. Journal of Nanostructures. 2025; 15(4):1849-1860.
Hussin F, Aroua M K, Daud W M A W. Textural characteristics, surface chemistry and activation of bleaching earth: A review. Chemical Engineering Journal. 2011; 170(1):90-106. https://doi.org/10.1016/j.cej.2011.03.065
Shamuratov Sanzharbek, Umid Baltaev, Umarbek Alimov, Namazov Shafoat, Sherzod Kurambaev, and Bazar Ibadullaev. Utilization Process Research of the Soap Industry Acid Waste Water with High Carbonate Phosphorite of Central Kyzylkum.E3S Web of Conferences. EDP Sciences. 2021. https://doi.org/10.1051/e3sconf/202126404079
Shamuratov Sanjarbek, Umid Baltaev, Sanobar Achilova, Umarbek Alimov, Shafoat Namazov, and Najimuddin Usanbaev. Enhancement of Availability of High Calcareous Phosphorite by Neutralization of Acid Effluent and Composting of Cattle Manure. E3S Web of Conferences. EDP Sciences. 2023. https://doi.org/10.1051/e3sconf/202337703004
Shamuratov Sanjarbek, Umid Baltaev, Olga Myachina, Umarbek Alimov, Elyor Atashev, and Tokhir Kuramboev. Agrochemical Efficiency of Slow Release Phosphate Fertilizers Derived on the Base of Phosphorite Activation. E3S Web of Conferences. EDP Sciences. 2023. https://doi.org/10.1051/e3sconf/202343403014
Sotimboev Ilgizarbek, Umidbek Baltaev, Sanjarbek Shamuratov, Ruzimov Shamsiddin, Umarbek Alimov, and Mirzabek Saporboyev. Technical and Economic Efficiency of Processing Acidic Wastewater from the Oil and Fat Industry into Necessary Agricultural Products. E3S Web of Conferences. EDP Sciences. 2024. https://doi.org/10.1051/e3sconf/202456303072
Turatbekova Aidai, Malokhat Abdukadirova, Sanjarbek Shamuratov, Bakhodir Latipov, Mirzabek Saporboyev, Jafar Shamshiyev, and Yusuf Makhmudov. Investigation of the Effect of Fertilizers on the Biochemical and Physical Characteristics of Carrots (Daucus Carota L.). E3S Web of Conferences. EDP Sciences. 2024. https://doi.org/10.1051/e3sconf/202456303074
Shamuratov S, Alimov U, Rifky M, Baltaev U, Ibragimova М, Kurambaev S, & Radjabov М. Investigation of the Kinetics of Cotton Soapstock Saponification under Ultrasonic Illumination. Eurasian Chemico-Technological Journal. 2025; 27(4):323–335. https://doi.org/10.18321/ectj1679
Boyjanov NI, Rakhimov UB, Ataullaev ZM, Boltayev MA, Serkayev QP, Khamidova MO. Mathematical analysis of the linear increase in SIO2 content during the activation of Navbakhor alkaline bentonite with hydrochloric acid. Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources. 2027; 342(3):90-99. https://doi.org/10.31643/2027/6445.33
Yuldasheva A P, Shamuratov S Kh, Kurambayev Sh R, & Radjabov M F. Mathematical analysis of CaO content variation in acidic wastewater and mineralized mass mixture from Central Kyzylkum phosphorite based on exponential decay model. Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources. 2026; 339(4):79-86. https://doi.org/10.31643/2026/6445.42
Baltayev U S, Shamuratov S X, Alimov U K, Madaminov A E, & Jabbarov M E. Extraction of P₂O₅ from the mineralized mass of the Central Kyzylkum using acidic wastewater generated from cotton soapstock processing: Scientific analysis based on equilibrium principles. Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources. 2027; 341(2):83-96. https://doi.org/10.31643/2027/6445.20
Shamuratov SX, Baltaev US, Alimov UK, Jabbarov ME, Madaminov AE. Sigmoid Neutralization Response of Acidic Soapstock Waste by Mineralized Phosphorite Residues: A 4-Parameter Logistic Approach. Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources. 2027; 342(3):80-89. https://doi.org/10.31643/2027/6445.32
Palvan K, et al. Information and Measuring System for Monitoring the Moisture Content of Grain and Grain Materials, 2025 IEEE 26th International Conference of Young Professionals in Electron Devices and Materials (EDM), Altai, Russian Federation. 2025, 2260-2265. https://doi.org/10.1109/EDM65517.2025.11096667
Komadel P, & Madejová J. Acid activation of clay minerals. In Bergaya F, Theng B K G, & Lagaly G. (Eds.), Handbook of clay science. Elsevier. 2006; 5:263–287. https://doi.org/10.1016/B978-0-08-098258-8.00013-4
Balci S. Structural property improvements of bentonite with sulfuric acid activation and a test in catalytic wet peroxide oxidation of phenol. International Journal of Chemical Reactor Engineering. 2019; 17(6):121776. https://doi.org/10.1515/ijcre-2018-0167
Terzić A, Pezo L, Andrić L, Pavlović V B, & Mitić V V. Optimization of bentonite clay mechano-chemical activation using artificial neural network modeling. Ceramics International. 2017; 43(6):4994–5004. https://doi.org/10.1016/j.ceramint.2016.11.058
Rouhani H, Farhadi F, Akbari Kenari M, Eskandari E, & Ramakrishna S. Selection of suitable bentonite and the influence of various acids on the preparation of a special clay for the removal of trace olefins from aromatics. Clay Minerals. 2021; 56(3):185. https://doi.org/10.1180/clm.2021.32
Aziz B K, Abdullah M A, & Kaufhold S. Kinetics of oil extraction from clay used in the lubricating oil re-refining processes and re-activation of the spent bleaching clay. Reaction Kinetics, Mechanisms and Catalysis. 2021; 132(1):1–18. https://doi.org/10.1007/s11144-020-01904-7
Didi M A, Makhoukhi B, Azzouz A, Villemin D. Colza oil bleaching through optimized acid activation of bentonite: A comparative study. Applied Clay Science. 2009; 42(3-4):336-344. https://doi.org/10.1016/j.clay.2008.03.014
Arfaoui S, Frini-Srasra N, & Srasra E. Modelling of the adsorption of the chromium ion by modified clays. Desalination. 2008; 222(1-3):474-481. https://doi.org/10.1016/j.desal.2007.03.014
Christidis G E, Scott P W, & Dunham A C. Acid activation and bleaching capacity of bentonites from the islands of Milos and Chios, Aegean, Greece. Applied Clay Science. 1997; 12(1-2):57-75. https://doi.org/10.1016/S0169-1317(97)00017-3
Foletto E L, Volzone C, & Porto L M. Clarification of cottonseed oil: How structural properties of treated bentonites by acid affect bleaching efficiency. Latin American Applied Research. 2006; 36(1):37–42.
Noyan H, Önal M, & Sarıkaya Y. The effect of sulphuric acid activation on the crystallinity, surface area, porosity, surface
acidity and bleaching power of a bentonite. Food Chemistry. 2007; 105(1):156-163. https://doi.org/10.1016/j.foodchem.2007.03.060
Chanturia V A, Minenko V G, Samusev A L, et al. Adsorption of rare earth elements at modified saponite. Journal of Mining Science. 2024; 60:485–493. https://doi.org/10.1134/S1062739124030153
Karimi L, & Salem A. Analysis of bentonite specific surface area by kinetic model during activation process in presence of sodium carbonate. Microporous and Mesoporous Materials. 2011; 141(1–3):81–87. https://doi.org/10.1016/j.micromeso.2010.10.031
Crundwell F K. The dissolution and leaching of minerals: Mechanisms, myths and misunderstandings. Hydrometallurgy. 2013; 139:132-148. https://doi.org/10.1016/j.hydromet.2013.08.003
Madejová J, & Komadel P. Baseline studies of the Clay Minerals Society source clays: Infrared methods. In CMS Workshop Lectures. Clay Minerals Society. 1998; 9:99-139.
Tyagi B, Chudasama C D, & Jasra R V. Determination of structural modification in acid activated montmorillonite clay by FT-IR spectroscopy. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2006; 64(2):273–278. https://doi.org/10.1016/j.saa.2005.07.018
Shattar SFA, et al. One-step acid activation of bentonite derived adsorbent for effective removal of contaminants. Scientific Reports. 2020; 10:20053. https://doi.org/10.1038/s41598-020-76723-w
Yaghmaeiyan N, Mirzaei M, & Delghavi R. Montmorillonite clay: Introduction and evaluation of its applications in different organic syntheses as catalyst: A review. Results in Chemistry. 2022; 4:100549. https://doi.org/10.1016/j.rechem.2022.100549
Tsakiri D, Douni I, & Taxiarchou M. Structural and surface modification of oxalic-acid-activated bentonites in various acid concentrations for bleaching earth synthesis-A comparative study. Minerals. 2022; 12(6):764. https://doi.org/10.3390/min12060764
Ayati B, Newport D, Wong H, Cheeseman C. Acid activated smectite clay as pozzolanic supplementary cementitious material. Cement and Concrete Research. 2022; 162:106969. https://doi.org/10.1016/j.cemconres.2022.106969
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2026 N.I. Boyjanov, G.M. Otajonova, B.B. Kendjayev, M.X. Matyakubova, N.K. Sabirova, A.T. Masharipov, I.R. Boyjanov, Q.P. Serkayev

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.









