A slurry emission off a pulp appeared after metallurgic gases wash of Balkhash copper smelting plant by spinning
DOI:
https://doi.org/10.31643/2019/6445.11Keywords:
metallurgic gases, flushing, pulp, cleansing sulphuric acid, slurry, straining, spinningAbstract
A sulphuric acid is obtained of the metallurgic gases after smelting of feed materials and matte converting preliminary cleaned dry or wet method. A pulp appears after wet gases cleaning containing sulphuric acid solution, slurry and amorphous selenium. The sulphuric acid production at the Balkhash copper smelting plant differs from the identic one at the Zheskazgan copper smelting plant by cleansing solutions spinning off and extracting slurry out of them by sedimentation. By this reason Balkhash copper smelting plant discharge pulp 7-14 times as much as Zheskazgan copper smelting plant of clarified liquor. Pulp is a valued man-made raw material to extract rhenium off the solution, selenium iodine off the slurry. At present, a sorption technology of rhenium extraction off the solution is developed and tested in the pilot scale. Selenium is a second component worth mentioning considering its production at the Balkhash copper smelting plant. This article analyzes prospect researches of various methods testing of clear solutions obtaining, faults and benefits of straining by spinning. The results are provided of the slurry amount effect and amorphous selenium in the pulp, the speed and time of rotation of the centrifuge rotor. A rotor spinning velocity is established to be the main factor has impact on pulp separation into the clear solution and residue of every slurry compound, including amorphous selenium by spinning. This method according to calculations allows to a substantial energy costs saving comparing the pulp heating-straining.
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ZagorodnyayaA.N. ShlamsernokislotnogotsekhaBalkhashskogomedeplavilnogozavoda–alternativnyjistochnik polucheniya selenanapredpriyatii. Obzor.(Slime of sulfuric acid workshop’s of balkhashcopper plant -alternative source of production of selenium at organization. Review.KompleksnoeIspolʹzovanieMineralʹnogosyrʹâ. 2018. 4(307),46–55. (in Russ.) https://doi.org/10.31643/2018/6445.29
AbishevaZ.S., ZagorodnyayaA.N., SharipovaA.S., SadykanovaS.E., SukurovB.M. Kachestvennyj I veshchestvennyj sostavy osadkov soderzhashchikhsya v rastvorakh ot promyvk I metallurgicheskikh gazov mednogo proizvodstva(The qualitative and material composition of the sediments contained in solutions from the washing of metallurgical gases of copper production).Materialy II-oj mezhdunarodnoj kazakhstansko-rossiyskoj konferentsii po khimii I khimicheskoj tekhnologii.(2nd Intern. Kazakh-Russian conf. on chemistry and chemical technology, dedicated to the 40th anniversary of the Karaganda State University of E.A. Buketov). Karaganda. Kazakhstan. 2012. I, 30-33. (in Russ.)
Abisheva Z.S., Zagorodnyaya A.N., Bekturganov N.S., Ospanov E.A., Ospanov N.A. Issledovaniye sorbtsii reniya iz proizvodstvennykh rastvorov promyvnoj sernoj kisloty Balkhashskogo medeplavilnogo zavoda na anionite A170(Researchings of rhenium sorption from the industrial solutions of the wash sulfuric acid of the Balkhash copper-smelting plant on anionite A170).Tsvetnyye metally=Non-ferrous metals. 2012. 7, 57-61. (in Russ.)
Zagorodnyaya A.N., Abisheva Z.S., Sadykanova S. E., Sharipova A. S. Podgotovka rastvorov ot promyvki metallurgicheskikh gazov mednogo proizvodstva dlya sorbtsionnogo izvlecheniya iz nikh reniya(Preparation of solutions from flushing of metallurgical gases of copper production for the sorption extraction of rhenium from them).Materialy II-oj mezhdunarodnoj kazakhstansko-rossiyskoj konferentsii po khimii i khimicheskoj tekhnologii.(2nd Intern. Kazakh-Russian conf. on chemistry and chemical technology, dedicated to the 40th anniversary of the Karaganda State University of E.A. Buketov). Karaganda. Kazakhstan. 2012.I,138-142. (in Russ.)
Zagorodnyaya A.N., Abisheva Z.S., Sadykanova S.E., Sharipova A.S. Izvlecheniye reniya iz stochnykh vod ot promyvki metallurgicheskikh gazov mednogo proizvodstva(Extraction of rhenium from wastewater from flushing of metallurgical gases of copper production).Sb. dokl. 2-oj mezhdunarodnoj nauchno-prakticheskojkonferentsii «Sovremennyye resursosberegayushchiye tekhnologii. Problemy i perspektivy».(2nd Intern. Kazakh-Russian conf. «Modern resource-saving technologies. Problems and prospects».) Odessa. 2012, 67-73. (in Russ.)
Zagorodnyaya A.N., Abisheva Z.S.,Sharipova A.S., Sadykanova S.E. Polucheniye perrenata ammoniya iz kislykh stochnykh vod ot promyvki metallurgicheskikh gazov pererabotki mednoy shikhty(Ammonium perrhenateobtaining from acid wastewater from washing metallurgical gases of copper charge processing).Kompleksnoye ispol'zovaniye mineral'nogo syr'ia. 2014. 2, 57-63. http://kims-imio.kz (in Russ.)
Agapova L. Ya., Zagorodnyaya A. N., Abisheva Z. S., Kilibayeva S. K., Altenova A. N. Ispol'zovaniye elektrodializa dlya polucheniya chistogo perrenata ammoniya iz tekhnicheskoy soli(Use of electrodialysis for obtaining of pure ammonia perrhenate from technical salt).Kompleksnoye ispol'zovaniye mineral'nogo syr'ia. 2014. 3, 71-77. http://kims-imio.kz (in Russ.)
Zagorodnyaya A.N., Abisheva Z.S., Sharipova A.S., Zhumabekov Zh.Zh. Polupromyshlennyye ispytaniya sorbtsionnoj tekhnologii izvlecheniya reniya iz stochnykh vod ot promyvki metallurgicheskikh gazov Balkhashskogo mednogo zavoda(Semi-industrial testings of sorption technology of rhenium extraction from the waste waters of Balkhash copper smelting plant metallurgical gas scrubbing).Tsvetnyye metally=Non-ferrous metals. 2016. 1, 49 -55. (in Russ.). http://dx.doi.org/10.17580/tsm.2016.01.08
Ionity v tsvetnoj metallurgii(ionites in non-ferrous metallurgy).Ed. K. B. Lebedeva.Moscow: Metallurgy, 1975. 352. (in Russ.).
Abdrakhmanova D.K. Kompleksnaya pererabotka promproduktov medeplavilnogo proizvodstva s polucheniyem soyedinenij tsvetnykh i redkikh metallov (Complex processing of industrial products of copper-smelting production with obtaining
compounds of non-ferrous and rare metals).Mat. 6-j mezhdunar. molodezhnoj nauchno-praktich. konf. «Innovatsionnyye tekhnologii v metallurgii i mashinostroyenii»("Innovative technologies in metallurgy and mechanical engineering"). Ekaterinburg, October 29 -November 1, 2012. Ekaterinburg: the Urals.University Press, 2012.729-730.(in Russ.).
Karelov S.V., Mamyachenkov S.V., Nabojchenko E.S. Tekhnogennyye otkhody medeplavilnogo proizvodstva i perspektivy ikh pererabotki (Technogenicwaste copper smelting production and the prospects for their processing).Tsvetnyye metally = Non-ferrous metals.-2000. 9.47-49. (in Russ.).
Voskresenskiy P. I. Tekhnika laboratornykh rabot.(Technique of laboratory work) Moscow: Khimiya. 1967. 551.(in Russ.).
Fridrikhsberg D. A. Kurs kolloidnoj khimii.(Course of colloid chemistry) Leningrad: Khimiya. 1984.368. (in Russ.).
Kudryavtsev A. A. Khimiya i tekhnologiya selena i tellura.(Chemistry and technology of selenium and tellurium). Moscow: Metallurgiya. 1967. 340. (in Russ.).
Sokolov V. I. Tsentrifugirovaniye.(Centrifugation). Moscow: Khimiya. 1976. 408. (in Russ.).
Trots E.S., Vorontsov K.B. Otsenka ehffektivnosti obezvozhivaniya shlam-lignina metodom tsentrifugirovaniya(Assessment of efficiency of dehydration slime lignin centrifugation method).Nauka-rastudent.ru. 2015. 06 (18). [Elektronnyy resurs] –Rezhim dostupa. URL: http://nauka-rastudent.ru/18/2709/.(accesdate:19.02.2019)
Suning Liu Kai, Huang Hongmin Zhu. Recovery of silicon powder from silicon wiresawing slurries by tuning the particle surface potential combined with centrifugation. Separation and Purification Technology. 2013. 118.. 448-454. (in Eng.). https://doi.org/10.1016/j.seppur.2013.07.011
Zhen Li, Jiaping Liu, QianTian. Method for controlling the absorbed water content of recycled fine aggregates by centrifugation.Construction and Building Materials. 2018.160.316-325. (in Eng.). https://doi.org/10.1016/j.conbuildmat.2017.11.068
Koltsov V.B., Kondrat'yeva O.V. Teoreticheskiye osnovy okruzhayushchej sredy(Theoretical Foundations of the Environment). Moscow: Prometej. 2018.734. (in Russ.).
Svetlov S.A., VolkovYu.P. Ochistka zhidkikh sred ot vysokodispersnoj tverdoj fazy s ispolzovaniyem osaditelnykh tsentrifug (Purification of liquids from highly dispersed solid phase using precipitation centrifuges). Khimicheskaya promyshlennost'= Chemical industry. 2004.81. 5. 230-235. (in Russ.).
Volkov Yu.P., Svetlov S.A. Tsentrobezhnaya ochistka tekhnologicheskikh zhidkostej ot tverdoy fazy(Centrifugal cleaning of process liquids from solid phase). Materialy i tekhnologii XXI veka: Tez.dokl. I Vserossiyskoj nauchno-prakt. konf. (Materials and technologies of the XXI century: Abstracts of reports. I All-Russian Scientific Practical. conf.) Moscow: TsEI «Khimmash». 2000. 235-236. (in Russ.).
Svetlov S.A., Pavlova N.V. Modelirovaniye protsessa tsentrobezhnogo razdeleniya suspenzij v bikonicheskom rotore tsentrifug(Simulation of the process of centrifugal separation of suspensions in a biconical centrifuge rotor).Khimicheskaya promyshlennost'= Chemical industry. 2004. 81.9.472-479. (in Russ.).
Vetoshkin A.G. Osnovy inzhenernoj zashchity okruzhayushchej sredy. Uchebnoye posobiye(Fundamentals of environmental engineering. Study guide.). Moscow: Infa-Inzhenenriya. 2016. 456. (in Russ.).
Khentse M., Armoes P., Lya-Kur-Yansen Y., Arvan E. Ochistka stochnykh vod(Wastewater treatment): M.: Mir .2006. 480. (in Russ.).
Tsentrifugirovaniye. Tsentrifugi (promyshlennyye) ot proizvoditelya Ishikawajima-Harima Heavy Industries Co.. Ltd. (IHI) -Yaponiya Tsentrobezhnoye filtrovaniye i osazhdeniye(Centrifugation, centrifuges (industrial) from the manufacturer Ishikawajima-Harima Heavy IndustriesCo., Ltd. (IHI) -Japan Centrifugal Filtration and Precipitation http://oil-filters.ru/centrifuges(acces date 02.19.2019). (in Russ.).
Rukovodstvo po preparativnoy neorganicheskoy khimii. (Handbook of preparative inorganic chemistry). Edited byBrauyera G. M.: 1956. 895. (in Eng.)
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