Slime from sulfuric acid shop of Balkhash copper-smelting factory – alternative source for production of selenium at the enterprise. Review

Authors

  • A.N. Zagorodnyaya “Institute of Metallurgy and Ore Beneficiation” JSC

DOI:

https://doi.org/10.31643/2018/6445.29

Keywords:

selenium, sulfuric acid shop slime, copper plant, qualitative, quantitative, granulometric, substantial composition.

Abstract

The article covers the problems of possibility for involving selenium from the slime of the sulfuric acid shop of the Balkhash Copper Smelting Plant (BCSP) into the sphere of its production. At pyrometallurgical processing of copper charge, selenium is sublimated and distributed among four waste products: washing sulfuric acid, slimes of sulfuric acid and electrolyte shop, and electrofilter dust. In the world, the main raw material for the production of selenium is copper electrolytic sludge (90 %) and sludge of sulfuric acid production of the chemical and pulp and paper industry (10 %). A comparative analysis of selenium content in the slimes of the metallurgical, chemical and pulp and paper industries showed that the content of selenium in the slimes of the sulfuric acid shops of the BCSP and “Kola Company” JSC is identical and much higher than in copper electrolytic slimes – the main source of selenium in the world. The qualitative, quantitative, granulometric and material compositions of the slime of the BCSP’s sulfuric acid shop are presented. It contains Pb, Se, Re, Al, Si, S, Ca, Fe, Cu, Zn, Sr, Cd, I, Hg, Ni, Br, Bi, As, Sb, Ag, Cr, Mg, Mo, Ti, Mn, and organic compounds (presumably, aliphatic acids). The content of some elements is several tens of percent, others – hundredths of a percent. Interest for the recovery is Se (4.6–32.3 5 wt. %), and furthermore are Re (0.14 wt. %), I (0.33 wt. % Hg (0.57 wt. %). Slime-forming element is lead in the form of its sulfate. Into the size class -0.4 + 0 the following are recovered Pb – 47.84 %, Se – 47.45 %, Re 55.31 %. The content of the elements in classes of different sizes is almost identical: Pb (56.7-58.1 wt. %), Se (4.00-4.51 wt. %), Re (0.10-0.16 wt. %.). Selenium in the slime is in the forms of the elemental – of three modifications, lead selenate and a substance containing the selenite anion. With the slime disposed to sewage treatment plants, 30-40 % of selenium, produced from copper electrolyte slime in Balkhash, is lost. Following facts are a strong argument for involving these slimes into the sphere of selenium production. They are the high content of selenium in slime of sulfuric acid shop, in perspective taken out as an independent product when introducing the technology of rhenium extraction from washing solutions, the presence of selenium production at the plant and the predicted selenium deficit in the world due to introduction of new technologies.

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Author Biography

A.N. Zagorodnyaya, “Institute of Metallurgy and Ore Beneficiation” JSC

Doctor of Technical Sciences,professor, Chief Researcher, JSC “Institute of Metallurgy and Ore Beneficiation “, laboratory of rare scattered elements.

References

NaumovA.V. Sostoyaniei perspektivy mirovogo rynka selena(State and prospects of the world selenium market).Tsvetnaya metallurgiya=Non-ferrous metallurgy.2007. 5,12–20(in Russ).

Kul ́chitskijN.A.Naumov A.V. Sovremennoe sostoyanie rynkov selena i soedinenijna ego osnove(The current state of the markets for selenium and compounds based on it)Tsvetnaya metallurgiya. Izvestiya vuzov=Non-ferrous metallurgy. Proceedings of high schools.2015.3,43-47. (in Russ). https://doi.org/10.17073/0021-3438-2015-3-40-48

Kul ́chitskijN.A.,Naumov A.V. Sovremennye optoelektronnye pribory na osnove selenida tsinka(Modern optoelectronic devices based on zinc selenide)Nanoinzheneriya=Nanoengineering.2014.1,19 –27. (in Russ).

Andersson B.A. Materials availability for large-scale thin-film photovoltaics.Progress in Photovoltaics.2000. 8. 61-76. https://doi.org/10.1002/(SICI)1099-159X(200001/02)8:1<61::AID-PIP301>3.0.CO;2-6

Green M.A. Improved estimates for Te and Se availability from Cu anode slimes and recent price trends. Progress in Photovoltaics. 2006.14. 743-751.(in Eng).

Gavrishchuk E.M. Polikristallicheskijselenid tsinka dlya infrakrasnojoptiki(Polycrystalline zinc selenide for infrared optics)Neorganicheskie materialy=Inorganic materials.2003. 39. 9,1031-1049.(in Russ).

KorovinS.S.,Bukin V.I., Fedorov P.I.,Reznik A.M. Redkie irasseyannye elementу(Rare and scattered elements). Moscow: MISiS. 2003. 3. 438.(in Russ).

Zelikman A. N.,Korshunov B. G. Metallurgiya redkikh metallov(Metallurgy of rare metals). Moscow: Metallurgy. 1991. 431. (in Russ).

Lebed A.B., Nabojchenko S.S., Shunin V.A. Proizvodstvo selena i tellura na OAO «Uralehlektromed»(Production of selenium and tellurium at UralelectromedOJSC).Ekaterinburg: Ural University. 2015. 112.(in Russ).

Mastyugin S.A.,VolkovaN.A.,NabojchenkoS.S.,.LastochkinaM.A. Shlamy elektroliticheskogo rafinirovaniya medi i nikelya. Monografiya(Sludge of electrolytic refining of copper and nickel. Monograph).Ekaterinburg: UrFU. 2013. 258.(in Russ).

Petrov G.V.,Chernyshev A.A.,Kovalev B.N.,Andreyev Yu.V. Sovershenstvovanie tekhnologii poputnogo polucheniya selena pri pererabotke anodnykhshlamov elektroliza medi(Perfection of technology of passing of selenium at processing of anode copper electrolysis slimes).Zapiski Gornogo instituta. Sankt-Peterburg=Notes of the Mining Institute. St. Petersburg.2011.192, 58-60.(in Russ).

Xue JIao Li, Hong Ying Yang, Zhe Nan Jin, Guo Bao Chen, and Lin Lin Тong. Transformation of selenium-containing phases in copper anode Slimes during

leaching.The Minerals, Metals & Materials Society. 2017. 69. 10. 1931-1938.(in Eng.).

Yasin Kilic, Guldem Kartal, Servet Timur. An investigation of copper and selenium recovery from copper anode slimes.International Journal of Mineral Processing. 2013. 124. 75-82. https://doi.org/10.1016/j.minpro.2013.04.006. (in Eng.).

Fu-yuan Zhang, Ya-jie Zheng, Guo-min Peng Selection of reductants for extracting selenium and tellurium from degoldized solution of copper anode slimes.Transactions of Nonferrous Metals Society of China. 2017. 27. 917 -924.https://doi.org/10.1016/S1003-6326(17)60108-0(in Eng.).

Dian-kun Lu, Yong-feng Chang, Hong-ying Yang, Feng Xie Sequential removal of selenium and tellurium from copper anode slime with high nickel content.Transactions of Nonferrous Metals Society of China. 2015. 25. 1307-1314.https://doi.org/10.1016/S1003-6326(15)63729-3(inEng.).

Mel ́nikov Yu.T., Kravtsova E.D.,Krinitsyn D.O.Gidrometallurgicheskie tekhnologii pererabotki shlamov elektrorafinirovaniya medi i nikelya(Hydrometallurgical technologies for processing slurries of copper and nickel electrorefining).Tsvetnyye metally=Non-ferrous metals.2017.5,44-48.DOI:10.17580/tsm.2017.05.06 (in Russ.).

Areshina N.S., Kasikov A.G., Malts I.E., Zenkevich T.R. Izvlechenie selena iz produktov gazoochistki OAO «Kolskaya GMK»(Extraction of selenium from gas cleaning products of OJSC KolasMMC). Tsvetnyye metally=Non-ferrous metals. 2011. 11, 62-65.(in Russ.).

Abisheva Z.S.,Zagorodnyaya A.N. Vklad instituta metallurgii i obogashcheniya vorganizatsyu proizvodstva soyedineniy reniya i izotopa osmij-187 v Kazakhstane(The contribution of the Institute of Metallurgy and Enrichment to the organization of the production of compounds of rhenium and the isotope of osmium-187 in Kazakhstan). Vestnik MITKhT= Herald ofMITHT.2013. 8. 3,34-48.(in Russ.).

Areshina N.S., Kasikov A.G., Malts I.E.,Kuznetsov V.Ya. Utilizatsiya nekonditsionnykh sernokislykh rastvorov i pulp gazoochistki kombinata «Severonikel» OAO «Kolskaya GMK»(Utilization of substandard sulfuric acid solutions and gas cleaning pulp of the «Severonickel»Combine,OJSC Kolas MMC). Izvestiya vuzov. Tsvetnaya metallurgiya= Proceedings of high schools. Non-ferrous metallurgy.2008. 8,32–38.(in Russ.).

Kasikov A.G., Areshina N.S.,Malts IE. Gidrometallurgicheskaya pererabotka otkhodov gazoochistki medno-nikelevogo proizvodstva(Hydrometallurgical processing of gas cleaning waste of copper-nickel production).Tsvetnyye metally –2010: Mater. 2-oj mezhdunar. Kongr.. Razdel VIII Promyshlennaya i ekologicheskaya bezopasnost. (Non-ferrous metals –2010: proceedings of 2ndInternation. Congress. Section VIII Industrial and environmental safety). Krasnoyarsk, Russia. 2010. 2 Sept. 721-727. (in Russ.).

Kudryavtsev A.A. Khimiya i tekhnologiya selena i tellura(Chemistry and technology of selenium and tellurium). Moscow: Metallurgy. 1968,339.(in Russ.).

Nepenin N.N. Proizvodstvo sulfitnojtsellyulozy(Production of sulphite pulp).Moscow:Forest industry.1976, 1. 624.(inRuss.).

Abisheva Z.S.,Zagorodnyaya A.N.,Bekturganov N.S., Ospanov E.A.,Ospanov N.A. Issledovanie sorbtsii reniya iz proizvodstvennykh rastvorov promyvnoy sernojkisloty Balkhashskogo medeplavil ́nogo zavoda na anionite A170(Study of sorption of rhenium from industrial solutions of washing sulfuric acid of the Balkhash copper smelting plant on anionite А170). Tsvetnyye metally=Non-ferrous metals.2012. 7,57-61.(in Russ.).

Zagorodnyaya A.N., Abisheva Z.S., Sadykanova SE., Sharipova A.S. Podgotovka rastvorov ot promyvki metallurgicheskikh gazov mednogo proizvodstva dlya sorbtsionnogo izvlecheniya iz nikh reniya(Preparation of solutions from flushing of metallurgical gases of copper production for the sorption extraction of rhenium from them). 2-ayamezhdunar. Kazakhstansko-Rossiyskoy konf. po khimii i khimicheskoy tekhnologii. posvyashchennoy 40-letiyu KarGU imeni. E. A. Buketova: mater. konf.(2ndIntern. Kazakh-Russian conf. on chemistry and chemical technology, dedicated to the 40thanniversary of the Karaganda State University ofE.A. Buketov). Karaganda. Kazakhstan. 2012. I.138-142.(in Russ.).

Abisheva Z.S., Zagorodnyaya A.N., Sharipova A.S.,Sadykanova S.E., Sukurov B.M. Kachestvennyj i veshchestvennyjsostavy osadkov. soderzhashchikhsya v rastvorakh ot promyvki metallurgicheskikh gazov mednogo proizvodstva(The qualitative and material composition of the sediments contained in solutions from the washing of metallurgical gases of copper production) 2-aya mezhdunar. Kazakhstansko-Rossiyskoy konf. po khimii i khimicheskoy tekhnologii. posvyashchennoy 40-letiyuKarGU imeni. E. A. Buketova: mater. konf.(2ndIntern. Kazakh-Russian conf. on chemistry and chemical technology, dedicated to the 40thanniversary of the Karaganda State University of E.A. Buketov). Karaganda. Kazakhstan. 2012.I, 30-33.

Linnik X.A., AmanzhovaL.U., Sharipova A.S., Zagorodnyaya A.N. Balrhash copper-smelting plant sulfuric acid workshop’s slime composition.Kompleksnoye ispolzovaniye mineralnogo syria = Complex use of mineral resources. 2017. 4,42–48.(in Eng.).

Khrapunov V.E.,Trebukhov S.A.,Marki I.A.,Tuleutay F.Kh.,Trebukhov A.A. Izvlechenie selena iz shlamov sernokislotnogo proizvodstva vakuumnym metodom(Extraction of selenium from slimes of sulfuric acid production by the vacuum method). Kompleksnoye ispolzovaniye mineralnogo syria=Complex use of mineral raw materials. 2004. 4,42 –48.(in Russ.).

Vasil ́ev B.T., Otvagina M.I. Proizvodstvo sernojkisloty(Production of sulfuric acid). Moscow: Chemistry. 1985. 383.(in Russ.)

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Published

2018-10-08

How to Cite

Zagorodnyaya, A. (2018). Slime from sulfuric acid shop of Balkhash copper-smelting factory – alternative source for production of selenium at the enterprise. Review. Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources, 307(4), 46–55. https://doi.org/10.31643/2018/6445.29