Methods for purifying table salt from the Bakhyt-Тany deposit

Authors

  • D.A. Urazkeldiyeva M.Auezov South Kazakhstan Research University
  • A.A. Kadirbayeva M.Auezov South Kazakhstan Research University
  • A.F. Minakovsky Belarusian State Technological University
  • N.K. Sarypbekova M.Auezov South Kazakhstan Research University
  • B.M. Smailov M.Auezov South Kazakhstan Research University

DOI:

https://doi.org/10.31643/2025/6445.24

Keywords:

sodium chloride, brines, table salt, salt purification methods, sodium phosphate.

Abstract

This article discusses modern methods of purifying table salt from the Bakhyt-Tany deposits. Currently, the demand for various methods of production and processing of table salt is increasing. Therefore, high-quality purification of table salt and its effective use is one of the urgent tasks. As an object of study, salts were taken from the Bakhyt-Tany deposit, located in the Sozak district of the Turkestan region. The main goal of the scientific work is to study methods for purifying and processing sodium chloride from impurities. Modern analytical methods were used during scientific research. To determine the physicochemical properties of table salt, PEM JSM 6610 LV, X-ray microanalysis Inca Energy-450, energy dispersive system-fluorescence spectroscopy, IR-Fourier spectrometer were chosen. As a result of the research work, it turned out that using only the lime-soda method itself, it is possible to purify salt from calcium and magnesium ions up to 90-93%. It has been established that when using the phosphate method of purifying a saline solution, the degree of purification from calcium and magnesium ions increases to 95-97%. To further increase the degree of purification, it was recommended to first purify the solution using the lime-soda method, and then purify the solution using the phosphate method. It has been established that with this method the degree of purification can be increased to 99%.

Downloads

Download data is not yet available.

Author Biographies

D.A. Urazkeldiyeva, M.Auezov South Kazakhstan Research University

PhD doctoral student, The higher School of chemical engineering and biotechnology, M.Auezov South Kazakhstan University, Shymkent, Kazakhstan.

A.A. Kadirbayeva, M.Auezov South Kazakhstan Research University

Candidate of technical sciences, Assistant Professor, The higher School of chemical engineering and biotechnology, M.Auezov South Kazakhstan University, Shymkent, Kazakhstan.

A.F. Minakovsky, Belarusian State Technological University

Candidate of Technical Sciences, Docent, Departament of science, Belarusian State Technological University, Minsk, Belarus.

N.K. Sarypbekova, M.Auezov South Kazakhstan Research University

Candidate of chemical sciences. Docent. The higher School of chemical engineering and biotechnology, M.Auezov South Kazakhstan University, Shymkent, Kazakhstan.

B.M. Smailov, M.Auezov South Kazakhstan Research University

PhD doctor, Department of scientific research, M.Auezov South Kazakhstan University, Shymkent, Kazakhstan.

References

Bishimbayev VK, Amreev DD, Kapsalyamov BA, Gapparova KM, Sarsenov A. Analız rynka súlfata natrıa ı ıssledovanıe vozmojnostı ego polýchenıa ız súlfatnıkov mestorojdenıa Jaksykylysh [Analysis of the sodium sulfate market and study of the possibility of its production from sulfate rocks of the Zhaksykylysh deposit]. Bulletin of Science of Southern Kazakhstan. 2019; 1(5):58-65. (in Rus).

Desyatov AV, Kruchinina NE, Novikov SV. Glýbokaıa pererabotka mıneralızovannyh shahtnyh vod s polýchenıem krıstalıcheskogo súlfata natrıa [Deep processing of mineralized mine water to produce crystalline sodium sulfate. Advances in chemistry and chemical technology]. 2016; 9:96-99. (in Rus).

Ren Z, Wei X, Li R, Wang W, Wang Y, Zhou Z. Highly selective extraction of lithium ions from salt lake brines with sodium tetraphenylborate as co-extractant, Separation and Purification Technology. 2021; 269:118756. https://doi.org/10.1016/j.seppur.2021.118756

Cipolletta G, Lancioni N, Akyol Ç, Eusebi AL, Fatone F. Brine treatment technologies towards minimum/zero liquid discharge and resource recovery: State of the art and techno-economic assessment, Journal of Environmental Management. 2021; 300:113681. https://doi.org/10.1016/j.jenvman.2021.113681

Zhang X, Ren Y, Ping L, Ma H, Liu C, Wang Y, Kong L, Shen W. Solid-liquid equilibrium for the ternary systems and atmospheric pressure, J. Chem. Eng. 2014; 12:3969-3974. https://doi.org/10.1021/je500854m

Anarbayev АА, Khegay R, Spabekova R, and etc. Investigation of the process of lithium chloride extraction from brine of the salt lakes of the aral sea region. International Journal of Innovative Technology and Exploring Engineering. 2019; 8(7):2235-2238.

Shen Y, Linnow K, Steiger M. Crystallization behavior and damage potential of Na2SO4 –NaCl mixtures in porous building materials. Cryst. Growth Des. 2020; 20(9):5974-5985. http://dx.doi.org/10.1021/acs.cgd.0c00671

Ren Z, Wei X, Li R, Wang W, Wang Y, Zhou Z. Highly selective extraction of lithium ions from salt lake brines with sodium tetraphenylborate as co-extractant. Separation and Purification Technology. 2021; 269:118756. http://dx.doi.org/10.1016/j.seppur.2021.118756

Pat. 2495825 C01В 3/14 RU. Sposob ochistki khlorida natriya [Method of purification of sodium chloride]. Fakeev AA, Polishchuk OM, Mursky GL. Opubl. 20.10.2013, 29. (in Russ.).

Pat. 1428 С01D 3/08 KG. Sposob ochıstkı solányh porod ot prımesnyh ıonov [A method for cleaning salt rocks from impurity ions] Kochkorova ZB, Kalchaeva BSh, Murzubraimov BM, Satybaldiev AS. Opubl. 30.03.2012 (in Russ.).

Khalil А, Mohammed S, Hashaikeh R, Hilal N. Lithium recovery from brine: Recent developments and challenges. Desalination. 2022; 528:115611. http://dx.doi.org/10.1016/j.desal.2022.115611

Section "Environmental Protection" for the project "Extraction of lake salt from the Bakhyt-Tany deposit in the Sozak district, Turkestan region", Shymkent, 2022 https://cloud.mail.ru/public/WuDV/DUyDS59W6

GOST Р 51574-2000. Common salt. Test methods. Publishing House of Standards, Moscow. (in Russ).

Li Zhu, YuLong Ma, ShaoYing Ge, YuYu Wang. Solid-liquid phase equilibria of the quaternary system. The Journal of Chemical Thermodynamics. 2022; 165:106658. https://doi.org/10.1016/j.jct.2021.106658

Anarbayev АА, Khegay R, Spabekova R, Kabylbekova BN, Dmitrevsky BА. Studying the process of lithium chloride extraction from the brine. News Nat. Acad. Sci. RK. 2020; 1(439):99-105. http://dx.doi.org/10.32014/2020.2518-170X.12

Shen W, Ren Y, Sun J. Solid-liquid phase equilibrium and phase diagram for the reciprocal quaternary system – Science Direct, Fluid Phase Equilib. 2016; 429:196-204. https://doi.org/10.1016/j.fluid.2016.09.005

Kadirbayeva AA, Kaldybayeva G, Iskakova T, Raiymbekov EB. As tuzynyng kuramyn zhane oni tazalaudi zertteu [Study of the composition of table salt and its purification]. Bulletin KazNTU. 2017; 3(121):605-609. (in Kaz.).

Anarbayev AA, Ormanova GM, Kabylbekova BN, Vysotskaya NA, Kucharov BK. Regularities of interaction of calcium chloride of distiller liquid with natural sodium sulfate. Rasayan J. Chem. 2020; 13(4):2173-2180. http://dx.doi.org/10.31788/RJC.2020.1345888

Xu Zhao, Qi Zhang, Haihong Wu, Xiaocui Hao, Liang Wang, Xiping Huang. Extraction of Lithium from Salt Lake Brine. Progress in Chemistry. 2017; 29(7):796-808. (In Chinese). https://doi.org/10.7536/PC170313

Dahmardeh H, Akhlaghi Amiri HA, Nowee SM. Evaluation of mechanical vapor recompression crystallization process for treatment of high salinity wastewater. Chemical Engineering and Processing - Process Intensification. 2019; 145:107682. http://dx.doi.org/10.1016/j.cep.2019.107682

Xingguo Luo, Xingbin Li, Chang Wei, Zhigan Deng, Ye Liu, Minting Li, Sanqiang Zheng, Xing Huang. Recovery of NaCl and Na2SO4 from high salinity brine by purification and evaporation. Desalination. 2022; 530:115631. http://dx.doi.org/10.1016/j.desal.2022.115631

Myerson A, Erdemir D & Lee A. (Eds.). Handbook of Industrial Crystallization (3rd ed.). Cambridge: Cambridge University Press. 2019. http://dx.doi.org/10.1017/9781139026949

Downloads

Published

2024-06-21

How to Cite

Urazkeldiyeva, D., Kadirbayeva, A., Minakovsky, A., Sarypbekova, N., & Smailov, B. (2024). Methods for purifying table salt from the Bakhyt-Тany deposit. Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources, 334(3), 19–25. https://doi.org/10.31643/2025/6445.24

Issue

Section

Engineering and technology