Microstructure and tribological study of TiAlCN and TiTaCN coatings

Authors

  • N. Bakhytuly “Institute of Metallurgy and Ore Beneficiation” JSC; Satbayev University
  • A. Kenzhegulov “Institute of Metallurgy and Ore Beneficiation” JSC; Satbayev University
  • М. Nurtanto University of Sultan Ageng Tirtayasa
  • A. Aliev University of Texas at Dallas
  • E. Kuldeev “Institute of Metallurgy and Ore Beneficiation” JSC; Satbayev University

DOI:

https://doi.org/10.31643/2023/6445.45

Keywords:

titanium carbonitride, magnetron sputtering, alloying, coefficient of friction, wear rate, wear resistance.

Abstract

The low coefficients of friction and wear rates of transition metal carbonitride make them excellent candidates for friction and wear applications. Coatings based on titanium carbonitride alloyed with Ta and Al were deposited using reactive magnetron sputtering on the surface of titanium VT1-0 and steel AISI 304. The effect of alloying titanium carbonitrides with Ta and Al and acetylene flow during deposition on the structure, composition, and tribological properties of the coating was studied. TiAlCN and TiTаCN coatings were deposited in various acetylene flows along with stable argon and nitrogen flows. Scanning electron microscopy, optical microscopy, X-ray phase analysis, and sliding wear test (ball-on-disk method) in two media were used to study the resulting coatings. The average coefficient of friction of the coating under friction without lubrication varied in the range of 0.13-0.85 and under friction with lubrication in the range of 0.0015-0.081. From the point of view of wear rate, it is shown that the most wear-resistant coating under friction conditions with and without lubrication is TiAlCN-2. The resulting coatings can be useful as protection for machine parts or tools that are subject to friction and wear.

Downloads

Download data is not yet available.

Author Biographies

N. Bakhytuly, “Institute of Metallurgy and Ore Beneficiation” JSC; Satbayev University

Researcher, JSC "Institute of Metallurgy and Ore Beneficiation", Satbayev University,  st. Shevchenko, 29/133, 050010, Almaty, Kazakhstan.

A. Kenzhegulov, “Institute of Metallurgy and Ore Beneficiation” JSC; Satbayev University

PhD, Researcher, JSC "Institute of Metallurgy and Ore Beneficiation", Satbayev University,  st. Shevchenko, 29/133, 050010, Almaty, Kazakhstan.  

М. Nurtanto, University of Sultan Ageng Tirtayasa

Ph.D., Researcher, JSC Department of Mechanical Engineering Vocational Education, Faculty of Teacher and Training Education, Sultan Agung Tirtayasa University, Banten, Indonesia.

A. Aliev, University of Texas at Dallas

Researcher Professor, "Alan MacDiarmid NanoTech Institute", University of Texas at Dallas, state Texas, USA. 

E. Kuldeev, “Institute of Metallurgy and Ore Beneficiation” JSC; Satbayev University

Candidate  of  Geological  and  Mineralogical  Sciences,  Vice-Rector  for  Corporate  Development  and  Strategic Planning, JSC "Institute of Metallurgy and Ore Beneficiation", Satbayev University,  st. Shevchenko, 29/133, 050010, Almaty, Kazakhstan.

References

Srinath MK, Ganesha MSP. Wear and corrosion resistance of titanium carbo-nitride coated Al-7075 produced through PVD. Bulletin of Material Science.2020;43:1-11. https://doi.org/10.1007/s12034-020-2069-9

Ramazanova JM, Zamalitdinova MG. Physical and mechanical properties investigation of oxide coatings on titanium. Kompleksnoe Ispolzovаnie Minerаlnogo Syrа = Complex Use Mineral Resources.2019;2:34-41. https://doi.org/10.31643/2019/6445.14

Yeshmanova GB, Smagulov DU, Blawert C. Plasma electrolytic oxidation technology for producing protective coatings of aluminum alloys. Kompleksnoe Ispolzovаnie Minerаlnogo Syrа = Complex Use of Minerаl Resources. 2021;317(2):78-93. https://doi.org/10.31643/2021/6445.21

KopfA, Haubner R, Lux B. Double-layer coatings on WC-Co hard metals containing diamond and titanium carbide/nitride. Diamond and Related Materials 2000;9:494-501. https://doi.org/10.1016/s0925-9635(00)00214-4

Matei AA, Pencea I, Branzei M, Tranca DE, et all. Corrosion resistance appraisal of TiN, TiCN and TiAlN coatings deposited by CAE-PVD method on WC-Co cutting tools exposed to artificial sea water. Applied Surface Science.2015;358:572-578. https://doi.org/10.1016/j.apsusc.2015.08.041

Su JF, Yu D, Nie X, Hu H. Inclined impact-sliding wear tests of TiN/Al2O3/TiCN coatings on cemented carbide substrates. Surface and Coatings Technology.2011;206:1998-2004. https://doi.org/10.1016/j.surfcoat.2011.09.067

Gil LE, Liscano S, Goudeau P, Le Bourhis E, et all. Effect of TiAlN PVD coatings on corrosion performance of WC–6%Co. Surface Engineering.2010;26:562-566. https://doi.org/10.1179/174329408x326399

Rakhadilov B, Buitkenov D, Idrisheva Z, Zhamanbayeva M, Pazylbek S, Baizhan D. Effect of Pulsed-Plasma Treatment on the Structural-Phase Composition and Tribological Properties of Detonation Coatings Based on Ti-Si-C. Coatings. 2021;11:795-806. https://doi.org/10.3390/coatings11070795

Iwai Y, Nanjo Y, Okazaki K, Tao M, Sentoku E. Application of Micro Slurry-Jet Erosion (MSE) for the Evaluation of Surface Properties of PVD TiN / TiCN Two-Layer Coatings. Tribology Online. 2017;12(2):49-57.

Zhang D, Shen B, Sun F. Study on tribological behavior and cutting performance of CVD diamond and DLC films on Co-cemented tungsten carbide substrates. Applied Surface Science.2010;256:2479-2489. https://doi.org/10.1016/j.apsusc.2009.10.092

Mansurov B, Medyanova B, Kenzhegulov A, Partizan G, Zhumadilov B, Mansurova M, Koztayeva U, Lesbayev B. Investigation of microdiamonds obtained by the oxygen-acetylene torch method. Eurasian Chemico-Technological Journal. 2017;19:163-167. https://doi.org/10.18321/ectj647

Razmi A, Yesildal R. Microstructure and mechanical properties of TiN/TiCN/TiC multilayer thin films deposited by magnetron sputtering. International Journal of Innovative Research and Reviews.2021;5:15-20. https://doi.org/10.20944/preprints201807.0127.v1

Matei AA, Pencea I, Stanciu SG, Hristu R, Antoniac I, Ciovica (Coman) E, Sfat CE, Stanciu GA. Structural characterization and adhesion appraisal of TiN and TiCN coatings deposited by CAE-PVD technique on a new carbide composite cutting tool. Journal of Adhesion Science and Technology.2015;29:2576-2589. https://doi.org/10.1080/01694243.2015.1075857

Zhu L, He J, Yan D, Liao H, Zhang N. Oxidation behavior of titanium carbonitride coating deposited by atmospheric plasma spray synthesis. Journal of Thermal Spray Technology. 2017;26(7):1701-1707. https://doi.org/10.1007/s11666-017-0620-z

Yang Y, GuoN, Li J. Synthesizing, microstructure and microhardness distribution of Ti−Si−C−N/TiCN composite coating on Ti−6Al−4V by laser cladding. Surface and Coatings Technology.2013;219(12):1-7. https://doi.org/10.1016/j.surfcoat.2012.12.038

Zhang J, Xue Q, Li S. Microstructure and corrosion behavior of TiC/Ti(CN)/TiN multilayer CVD coatings on high strength steels. Applied Surface Science.2013;280:626-631. https://doi.org/10.1016/j.apsusc.2013.05.037

Lou J, Gao Z, Zhang J, He H, Wang X. Comparative investigation on corrosion resistance of stainless steels coated with titanium nitride, nitrogen titanium carbide and titanium-diamond-likecarbon films. Coatings.2021;11:1543. https://doi.org/10.3390/coatings11121543

Mamaeva AA, Kenzhegulov AK, Panichkin AV, Kshibekova BB, Bakhytuly N. Deposition of carbonitride titanium coatings bymagnetron sputtering and its effect on tribo-mechanical properties. Kompleksnoe Ispolzovаnie Minerаlnogo Syrа = Complex Use of Minerаl Resources. 2022;321(2):65-78. https://doi.org/10.31643/2022/6445.19

Mamaeva A, Kenzhegulov A, Panichkin A, Alibekov Z, Wieleba W. Effect of Magnetron Sputtering Deposition Conditions on the Mechanical and Tribological Properties of Wear-Resistant Titanium Carbonitride Coatings. Coatings.2022;12(2):193. https://doi.org/10.3390/coatings12020193

Olteanu C, Munteanu D, Ionescu C, Munteanu A. Tribological characterisation of magnetron sputtered Ti(C, O, N) thin films. International Journal of Materials and Product Technology. 2010;39:186-194. https://doi.org/10.1504/ijmpt.2010.034270

Azlan MN, Hajer SS, Halimah MK, et al. Comprehensive comparison on optical properties of samarium oxide (micro/nano) particles doped tellurite glass for optoelectronics applications. J Mater Sci: Mater Electron. 2021; 32:14174-14185. https://doi.org/10.1007/s10854-021-05961-z

Zhou R, Ju H, Liu Sh, Zhao Z, Xu J, etc all. The influences of Ag content on the friction and wear properties of TiCN–Ag films. Vacuum. 2022, 110719. https://doi.org/10.1016/j.vacuum.2021.110719

Kenzhegulov A, Mamaeva A, Panichkin A, Alibekov Z, Kshibekova B, Bakhytuly N, Wieleba W. Comparative Study of Tribological and Corrosion Characteristics of TiCN, TiCrCN, and TiZrCN Coatings. Coatings.2022;12:564. https://doi.org/10.3390/coatings12050564

Charitidis CA. Nanomechanical and nanotribological properties of carbon-based thin films: a review. International Journal of Refractory Metals and Hard Materials. 2010; 28(1):51-70.

Zeng Y, Qiu Y, Mao X, et al. Superhard TiAlCN coatings prepared by radio frequency magnetron sputtering, Thin Solid Films . 2015;584:283-288. http://dx.doi.org/10.1016/j.tsf.2015.02.068

Stueber M, Barna PB, Simmonds MC, Albers U, etc all. Constitution and microstructure of magnetron sputtered nanocomposite coatings in the system Ti-Al -N-C. Thin Solid Films.2005;493:104-112. https://doi.org/10.1016/j.tsf.2005.07.290

Braic M, Balaceanu M, Vladescu A, Zoita CN, Braic V. Study of (Zr,Ti)CN, (Zr,Hf)CN and (Zr,Nb)CN films prepared by reactive magnetron sputtering. Thin Solid Films. 2011;519:4092-4096. https://doi.org/10.1016/j.tsf.2011.01.375

Zhang X, Jianqing J, Zeng Y, et al. Effect of carbon on TiAlCN coatings deposited by reactive magnetron sputtering. Surface & Coatings Technology. 2008;203:594-597.

Kenzhegulov АК, Mamayeva AA, Panichkin AV. Adhesion properties of calcium phosphate coatings on titanium. Kompleksnoe Ispolzovаnie Minerаlnogo Syrа = Complex Use of Minerаl Resources. 2017;3:35-41.

KenzhegulovAK. et al. Investigation of the adhesion properties of calcium-phosphate coating to titanium substrate with regards to the parameters of high-frequency magnetron sputtering. Acta Bioeng. Biomech. 2020;22:111-120.

Mamaeva AA, Kenzhegulov AK, Panichkin AV. A Study of the Influence of Thermal Treatment on Hydroxyapatite Coating.Protection of Metals and Physical Chemistry of Surfaces. 2018; 54( 3):448-452.

Mamaeva АА, Kenzhegulov АК, Panichkin АV, Shah А. Obtaining hydroxyapatite coatings by mechanochemical interaction. Kompleksnoe Ispolzovаnie Minerаlnogo Syrа = Complex Use of Minerаl Resources. 2020;314(3)76-83.

Mahdipoor M, Mahboubi F, Ahangarani S, Raoufi M, Elmkhah H. The Influence of Plasma Nitriding Pre-Treatment on Tribological Properties of TiN Coatings Deposited by PACVD. Journal of Materials Engineering and Performance. 2011;20:1-7. https://doi.org/10.1007/s11665-011-9971-7

Lackner JM, Waldhause W, Ebner R, Keckes J, Schoberl T. Room temperature deposition of (Ti, Al)N and (Ti, Al)(C, N) coatings by pulsed laser deposition for tribological applications, Surface & Coatings Technology. 2004;177,178:447-452.

Zhang X, Qiu Y, Tan Zh, Lin J, Xu A, Zeng Y, Moore JJ, Jiang J. Effect of Al content on structure and properties of TiAlCN coatings prepared by magnetron sputtering. Journal of Alloys and Compounds. 2014;617:81-85.

Zheng XH, Tu JP, Gu B, Hu SB. Preparation and tribological behavior of TiN/a-C composite films deposited by DC magnetron sputtering. Wear. 2008;26:261-265.

Wang Q, Zhou F, Chen K, Wang M, Qian T. Friction and wear properties of TiCN coatings sliding against SiC and steel balls in air and water. Thin Solid Films. 2011;519:4830-4841.

Downloads

Published

2023-03-24

How to Cite

Bakhytuly, N., Kenzhegulov, A., Nurtanto М., Aliev, A., & Kuldeev, E. (2023). Microstructure and tribological study of TiAlCN and TiTaCN coatings . Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources, 327(4), 99–110. https://doi.org/10.31643/2023/6445.45