Investigation of zinc leaching from clinker with pretreatment of raw materials by ultrahigh frequency radiation (microwave)
DOI:
https://doi.org/10.31643/2026/6445.35Keywords:
leaching, zinc, clinker, ultrahigh frequency radiation.Abstract
The processing of zinc-containing man-made raw materials is an important task from the point of view of rational use of natural resources and reducing the environmental burden. In recent years, there has been a growing interest in efficient methods of processing such materials, since zinc is an important metal for industry. The leaching of zinc from raw materials with a solution of sulfuric acid is a key step in the hydrometallurgical production of zinc. Optimizing this process is crucial to increase the efficiency of its extraction, reduce costs, and minimize negative environmental impacts. We have investigated the process of leaching zinc from man-made raw materials with a solution of sulfuric acid, with pretreatment of raw materials with microwave radiation. Optimal leaching parameters have been determined. Clinker, a residual product of zinc ore calcination, was used as the starting material. The zinc content in clinker is 1.25%. It is shown that high zinc recovery is achieved after preliminary exposure to microwave radiation at a temperature of 600 °C. The effect of solvent concentration, the ratio of solid and liquid phases, and temperature on the degree of zinc extraction has been studied.
Downloads
References
Nayak A, Jena MS, Mandre NR. Beneficiation of lead-zinc ores—A review. Miner. Process. Extr. Metall. Rev. 2021; 43:1-20. https://doi.org/10.1080/08827508.2021.1903459
TSINK. Mirovoy reyting stran [ZINC. World ranking of countries]. 2022. (in Russ). https://nedradv.ru/nedradv/ru/msr?obj=ca79a46078f5785d6a24f2c3830d0b9
Esezobor DE, Balogun SA. Zinc accumulation during recycling of iron oxide wastes in the blast furnace. Ironmaking & Steelmaking. 2006; 33(5):419-425. https://doi.org/10.1179/174328106X114020
Muammer Kaya, Shokrullah Hussaini, Sait Kursunoglu, Critical review on secondary zinc resources and their recycling technologies, Hydrometallurgy. 2020; 195:105362. https://doi.org/10.1016/j.hydromet.2020.105362
Yevtushevich II, Dzgoev ChT, Epifanov AV, Gudkov SS, Yemelyanov YuE, Belikov SV. Avtoklavno-pirometallurgicheskiy sposob pererabotki zolotosoderzhashchikh i svintsovo-tsinkovykh kontsentratov [Autoclave-pyrometallurgical method of processing gold-containing and lead-zinc concentrates] Journal of Siberian Federal University. Chemistry. 2017; 1. (in Russ). https://cyberleninka.ru/article/n/avtoklavno-pirometallurgicheskiy-sposob-pererabotki-zolotosoderzhaschih-i-svintsovo-tsinkovyh-kontsentratov
Kozlov PA. Extraction of a range of non-ferrous and rare metals from industrial waste: Physico-chemical basis and technical solutions. Tsvetnye Metally. 2020; 5:28-36. https://doi.org/10.17580/tsm.2020.05.05
Kolesnikov A, Fediuk R, Kolesnikova O, Akhmetova E, Shal A. Processing of Waste from Enrichment with the Production of Cement Clinker and the Extraction of Zinc. Materials. 2022; 15(1):324. https://doi.org/10.3390/ma15010324
Abdel-Aal EA. Kinetics of sulfuric acid leaching of low-grade zinc silicate ore, Hydrometallurgy. 2000; 55(3):247-254. ISSN 0304-386X. https://doi.org/10.1016/S0304-386X(00)00059-1
Ruşen A, Sunkar AS, Topkaya YA. Zinc and lead extraction from Çinkur leach residues by using hydrometallurgical method, Hydrometallurgy. 2008; 93(1–2):45-50. https://doi.org/10.1016/j.hydromet.2008.02.018
Kenzhaliyev B, Surkova T, Yessimova D, Baltabekova Z, Abikak Y, Abdikerim B, Dosymbayeva Z. Extraction of noble metals from pyrite cinders. ChemEngineering. 2023; 7(1):14. https://doi.org/10.3390/chemengineering7010014
Kenzhaliyev B, Surkova T, Yessimova D, Abikak Y, Mukhanova A, Fischer D. On the question of the complex processing of pyrite cinders. Inorganics. 2023; 11(4):171. https://doi.org/10.3390/inorganics11040171
Abdulvaliev RA, Surkova TYu, Baltabekova ZhA, Yessimova DM, Stachowicz M, Smailov KM, Dossymbayeva ZD, Berkinbayeva AN. Effect of amino acids on the extraction of copper from sub-conditional raw materials. Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources. 2025; 335(4):50-58. https://doi.org/10.31643/2025/6445.39
Kiorescu AV. Biovyshchelachivaniye nikelya, medi i kobal'ta iz predvaritel'no obrabotannoy svch-izlucheniyem rudy [Bioleaching of Nickel, Copper and Cobalt from Microwave Pre-Treated Ore] Successes of modern Natural Science. 2019; 12(1):51-56. (in Russ). https://doi.org/10.17513/use.37268
Fuzailov OU, Sayfullaev FI, and Mezhidova I, Zhabborova SG. Issledovaniye sposobov intensifikatsii protsessa obzhiga sul'fidnykh zolotosoderzhashchikh kontsentratov s primeneniyem mikrovolnovogo izlucheniya [Study of methods for intensifying the roasting process of sulphide gold-bearing concentrates using microwave radiation]. Journal of achievements in the field of engineering technologies. 2022; 2(6). (in Russ). https://doi.org/10.24412/2181-1431-2022-2-43-46
Ma A, Li J, Chang J, Zheng X. Mechanism Analysis and Experimental Research on Leaching Zn from Zinc Oxide Dust with an Ultrasound-Enhanced NH3-NH4Cl-H2O System. Sustainability. 2024; 16(7): 2901. https://doi.org/10.3390/su16072901
Li S, Wang H, Wang S, et al. Study on the kinetics and mechanism of ultrasonic-microwave synergistic enhancement for leaching indium from zinc oxide dust. Chem. Pap. 2024; 78: 3667-3685. https://doi.org/10.1007/s11696-024-03338-0
Wankun Wang, Fuchun Wang. Enhancing the extraction of germanium from zinc oxide dust through microwave roasting and the underlying mechanism, Chemical Engineering and Processing - Process Intensification. 2024; 206: 110050. https://doi.org/10.1016/j.cep.2024.110050
Molodtsova MA, Sevastyanova YuV. Vozmozhnosti i perspektivy ispol'zovaniya mikrovolnovogo izlucheniya v promyshlennosti (obzor) [Possibilities and Prospects of Using Microwave Radiation in Industry (Review)]. Lesn. zhurn. 2017; 2:173-187. (Higher Ed. studies. establishments). (in Russ). https://doi.org/10.17238/issn0536-1036.2017.2.173
Ryazanov AG, Kazbekova KK, Baryshev IS, Senin AV, Mikhailov GG. Issledovaniye protsessa vozdeystviya elektromagnitnogo polya svch na nagrev tsinksoderzhashchikh produktov [Study of the process of influence of microwave electromagnetic field on heating of zinc-containing products] Bulletin of SUSU. The Metallurgy series. 2021; 21(2):5-17. (in Russ). https://cyberleninka.ru/article/n/issledovanie-protsessa-vozdeystviya-elektromagnitnogo-polya-svch-na-nagrev-tsinksoderzhaschih-produktov
Kenzhaliyev B, Surkova T, Berkinbayeva A, Baltabekova Zh, Smailov K. Harnessing Microwave Technology for Enhanced Recovery of Zinc from Industrial Clinker. MDPI, Q-2. Metals. 2024; 14:699. https://doi.org/10.3390/met14060699
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2025 A.N. Berkinbaeva, T.Yu. Surkova, Z.D. Dosymbayeva, N.S. Umirbekova, A.A. Kebekbaeva, N.A. Kyussubayeva

This work is licensed under a Creative Commons Attribution 4.0 International License.