Ore treatment hydrogen peroxide during heap leaching of gold

Authors

  • Ye.K. Yessengarayev The Branch of the RSE «NC CPMS RK» State Scientific-Industrial Association of Industrial Ecology «Kazmekhanobr», Almaty, Kazakhstan
  • B.N. Surimbayev Al-Farabi Kazakh National University, Almaty, KZ
  • B.S. Baimbetov Satbayev University, Almaty, Kazakhstan
  • S.V. Mamyachenkov Head of Chair, Department of Non-Ferrous Metallurgy, Ural Federal University named after the first President of Russia B.N. Yeltsin, Ekaterinburg, Russia
  • T.S. Kanaly Laboratory of physical and analytical methods, Almaty, Kazakhstan

DOI:

https://doi.org/10.31643/2021/6445.01

Abstract

Over the past century, many problems have been focused on the problems of low leaching rate of gold and methods have been developed to intensify the leaching of gold. Among these methods, the use of hydrogen peroxide to accelerate the leaching of gold is known. In order to intensify the leaching process, the indicators of cyanide leaching of gold from ore using hydrogen peroxide were studied. This article presents the results of assay-gravimetric, chemical, and mineralogical analyses of gold-bearing ore from the Sari Gunay Deposit (Iran). The content of sulfide sulfur ore belongs to the category of low-sulphide, by oxidation of sulphur (50.70%) to the category of oxidized ores. Thermodynamic analysis of possible reactions of ore components with hydrogen peroxide is carried out. Laboratory studies on cyanide leaching of gold have shown that the maximum recovery of gold is 52.92% at a concentration of hydrogen peroxide of 0.5%, the recovery of gold without ore treatment is 52.03%. The results of laboratory and column tests with and without treatment with hydrogen peroxide (H2O2–0.5%) were compared. Treatment of gold-bearing ore with hydrogen peroxide during heap leaching of gold increases gold recovery by 1.2% and amounts to 55.89%, without treatment - 54.69%. This increases the consumption of sodium cyanide by 0.04 kg/t.

 

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Author Biographies

Ye.K. Yessengarayev, The Branch of the RSE «NC CPMS RK» State Scientific-Industrial Association of Industrial Ecology «Kazmekhanobr», Almaty, Kazakhstan

PhD student, Researcher Laboratory of precious metalsof, Satbayev University, Almaty, Kazakhstan.

B.N. Surimbayev, Al-Farabi Kazakh National University, Almaty, KZ

PhD, Senior Researcher, Laboratory of precious metals, The Branch of the RSE «NC CPMS RK» State Scientific-Industrial Association of Industrial Ecology «Kazmekhanobr», Almaty, Kazakhstan; - Senior Lecturer, Chair of Analytical, Colloid Chemistry and Technology of Rare Elements, Department of Chemistry and Chemical Technology

B.S. Baimbetov, Satbayev University, Almaty, Kazakhstan

Candidate of Technical Sciences, Associate Professor.

S.V. Mamyachenkov, Head of Chair, Department of Non-Ferrous Metallurgy, Ural Federal University named after the first President of Russia B.N. Yeltsin, Ekaterinburg, Russia

Doctor of Technical Sciences, Professor.

T.S. Kanaly, Laboratory of physical and analytical methods, Almaty, Kazakhstan

Junior researcher.

References

Van Zyl, D. J., Hutchison, I. P., & Kiel, J.E. (1988). Introduction to evaluation, design, and operation of precious metal heap leaching projects. Society of Mining Engineers, Littleton. Colorado. VII. 372.(in Eng.)

Surimbayev B.N., Baikonurova A.O., Bolotova L.S. (2017).Prospects for the development of the process of intensive cyanidation of gold-containing products in the Republic of Kazakhstan. News of the National Academy of Sciences of the Republic of Kazakhstan. Series of geology and technology sciences. Almaty, Kazakhstan, 4(424): 133–141.(in Eng.)

Abubakriev, A. T., Koizhanova, A. K., Magomedov, D. R., Erdenova, M. B., Abdyldaev, N. N. (2019). Leaching of gold-containing ores with application of oxidation activators. Kompleksnoe Ispolʹzovanie Mineralʹnogo syrʹâ/Complex Use of Mineral Resources/Mineraldik Shikisattardy Keshendi Paidalanu, 3(310), 10–15. https://doi.org/10.31643/2019/6445.23 (in Eng.)

Kenzhaliyev B.K., Koizhanova A.K., Magomedov D.R., Kamalov E.M., Erdenova M.B., Abdyldaev N.N. (2020). A study of the biohydrometallurgical method for extracting gold from flotation tailings.Metalurgija. 59, 4, 477 -480.(in Eng.)

Sorokin I.P. (1958). Izucheniye usloviy rastvoreniya zolota i serebra v tsianistykh rastvorakh pri nizkikh temperaturakh(Studying the conditions for the dissolution of gold and silver in cyanide solutions at low temperatures). Trudy VNII-1. (Transactions of VNII-1.) Magadan Russia. No 33, 13-69 (in Russ.)

Yessengarayev Ye.К., Baimbetov B.S., Bolotova L.S., Kanaly Ye.S., Akjerkenov M.D. (2018). Vliyaniye perekisi vodoroda na vyshchelachivaniye zolota(Effect of hydrogen peroxide on gold leaching).Mezhdunarodnaya nauchno-prakticheskaya konferentsiya «Innovatsii v kompleksnoy pererabotke mineral'nogo syr'ya»(International scientific-practical conference «Innovations in the complex processing of mineral raw materials).Almaty, 90-91. ISBN 978-601-06-5370-2 (in Russ.)

Huang Kong-xuan.(1996).New advantages on gold extraction in foreign countries. Hydrometallurgy,9-18 (in Chinese.)

Guzman L, Sgarra M, Chimenos J M, Fernandez M A, Espiell F. (1999). Gold cyanidation using hydrogen peroxide. Hydrometallurgy. 52, 21-35. https://doi.org/10.1016/S0304-386X(99)00006-7 (in Eng.)

Turysbekova G.S., Meretukov M.A., Bektaj E.K. (2015). Zoloto: innovacii v himii I metallurgii(Gold: Innovations in Chemistry and Metallurgy). Almaty,117. ISBN: 978-601-228-838-4, 117-223-228 (in Russ.)

Botz, M.M., Mudder, T.I., Akcil, A.U. (2016). Cyanide treatment: physical, chemical, and biological processes. In Gold ore processing, Elsevier. 619-645. https://doi.org/10.1016/B978-0-444-63658-4.00035-9 (in Eng.)

Breuer, P., Sutcliffe, C., Meakin, R. (2010). Comparison of industrial cyanide destruction processes. 25th International Mineral Processing Congress -IMPC2010, 7, 1483–1493. http://hdl.handle.net/102.100.100/109330?index=1 (in Eng.)

Kitis, M., Akcil, A., Karakaya, E., Yigit, N.O. (2005). Destruction of cyanide by hydrogen peroxide in tailings slurries from low bearing sulphidic gold ores. Miner. Eng. 18, 353–362. https://doi.org/10.1016/j.mineng.2004.06.003 (in Eng.)

Longley, R.J., McCallum, A., Katsikaros, N. (2003). Intensive cyanidation: onsite application of the InLine Leach Reactor to gravity gold concentrates. Miner. Eng. 16, 411–419. https://doi.org/10.1016/S0892-6875(03)00054-2 (in Eng.)

Surimbayev B., Bolotova L., Mishra B., Baikonurova A. (2018). Intensive cyanidation of gold from gravity concentrates ina drum-type apparatus, News of the National Academy of Sciences of the Republic of Kazakhstan.Series of geology and technical sciences.5, 431, 32–37. https://doi.org/10.32014/2018.2518-170X.7 (in Eng.)

Surimbayev B., Bolotova L., Baikonurova A., ShalgymbayevS. (2019). Acetic acid application as an activating reagent in the intensive cyanidation of gravity concentrates. Kompleks. ispolʹzovanie Miner. syrʹâ/Complex Use Miner. Resour. shikisattardy Keshendi Paid.1, 308, 83–88. https://doi.org/10.31643/2019/6445.10 (in Eng.)

Lawes, B.C., Mathre, O.B. (1971). Process for detoxifying cyanide waste waters. U.S. Patent No. 3,617,582.Washington, DC: U.S. Patent and Trademark Office, application 15.05.1969, publication 02.11.1971. (in Eng.)

Lobanov V.G., Timofeev Е.I., NabiullinF.М., Nacharov V.B., Tretyakov А.V., Filonov N.А., Mikov S.V., Gorbut V.N., Makovskaya O.Yu., Starkov А.М.(2017). Sposob tsianistogo vyshchelachivaniya zolota i serebra(Method of cyanic leaching of gold and silver).Pat. RUNo. 2624751C1,application11.04.2016, publication06.07.2017, Bull. No 19 (in Russ.)

Yessengarayev Ye.К., Baimbetov B.S., Mamyachenkov S.V., Surimbayev B.N., Prozor N.G.(2020). Izucheniye protsessa tsianidnogo vyshchelachivaniya zolota s primeneniyem atsetata natriya pri razlichnoy krupnosti rudy. [Study of the process of cyanide leaching of gold using sodium acetate at different ore sizes].Kompleksnoe Ispolʹzovanie Mineralʹnogo syrʹâ/Complex Use of Mineral Resources/Mineraldik Shikisattardy Keshendi Paidalanu,No1 (312),59-68. https://doi.org/10.31643/2020/6445.08 (in Russ.)

Yessengarayev Ye.К., Baimbetov B.S., Mamyachenkov S.V., Surimbayev B.N.(2020). Izucheniye veshchestvennogo sostava zolotosoderzhashchey rudy mestorozhdeniya Sari-Gunay. [Study of the material composition of gold-containing ore from the Sari-Gunai deposit].Gornyy zhurnal Kazakhstana/Mining Journal of Kazakhstan/Qazaqstannyń taý-kenjýrnaly, No2.6-11 (in Russ.)

Yessengarayev Ye. K., Baimbetov B. S., Surimbayev B. N. (2020).Studies on heap leaching of gold with the addition of sodium acetate as an intensifying reagent. Non-ferrous Metals. 2, 25–30. https://doi.org/10.17580/nfm.2020.02.04 (in Eng.)

Shumilova L.V., Reznik J.N., Zykov N.V., Dobromyslov J.P., Konareva T.G. (2009). Sposob kuchnogo vyshchelachivaniya zolota iz okislennykh i smeshannykh rud(Method of heap leaching of gold out of oxidised and mixed ores). Pat.RU No. 2361076C1,application 06.12.2007, publication. 10.07.2009, Bull. No 19 (in Russ.)

Karimi, P., Abdollahi, H., Amini, A., Noaparast, M., Shafaei, S.Z., Habashi, F. (2010).Cyanidation of gold ores containing copper, silver, lead, arsenic and antimony. Int. J. Miner. Process. 95 (1–4),68–77. https://doi.org/10.1016/j.minpro.2010.03.002 ISSN 0301-7516 (in Eng.)

Thiago Oliveira Nunan, Isabella Lima Viana, Guilherme C. Peixoto, Herbert Ernesto, Daniel Martin Verster, Jose Henrique Pereira, Jose M. Bonfatti, Luiz Alberto Cesar Teixeira. (2017).Improvements in gold ore cyanidation by pre-oxidation with hydrogen peroxide. Minerals Engineering. Vol. 108.67-70. https://doi.org/10.1016/j.mineng.2017.01.006 (in Eng.)

Marsden J., House I. (2006). The Chemistry of Gold Extraction. Society for Mining, Metallurgy and Exploration. 2nd edition. West Sussex, England: Ellis Horwood. ISBN 10: 0873352408 / ISBN 13: 9780873352406 (in Eng.)

Beisembaev B.B., Kenzhaliev B.K., Absalyamov H.K., Govyadovskaya O.Yu., Kopenov М.K., Tursynbayeva A.K.(2000). Sposob kuchnogo vyshchelachivaniya zolotosoderzhashchikh rud(Method for heap leaching of gold-bearing ores.). Pat.KZ No 9446,application17.08.1999, publication15.09.2000, Bull. No 9 (in Russ.).

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Published

2021-02-09

How to Cite

Yessengarayev, Y., Surimbayev, B., Baimbetov, B., Mamyachenkov, S., & Kanaly, T. (2021). Ore treatment hydrogen peroxide during heap leaching of gold. Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources, 316(1), 5–14. https://doi.org/10.31643/2021/6445.01