Investigation of the anticorrosion properties of nanoСЕС in amine environments

Authors

  • А.Е. Kemelzhanova Al-Farabi KazNU
  • K. Mukasev Al-Farabi KazNU
  • G.Sh. Yar-Mukhamedova Al-Farabi KazNU
  • Th. Lampke Technische Universität Chemnitz

DOI:

https://doi.org/10.31643/2020/6445.17

Keywords:

nano-composite coatings, corrosion resistance, amine media, protective properties, carbon steel.

Abstract

 It is known that of the methods for purifying gas fraction from hydrogen sulfide is amine treatment. Various types of amines are used to remove hydrogen sulphide, carbon dioxide and carbon dioxide from petroleum gases. The choice of specific amine depends on the needs of the process. Mono-ethanolamine (MEA) (C2H4OH) NHand diethanolamine (DEA) (C2H4OH) 2NH are commonly used. Both are ammonia derivatives. The develop recommendations on the choice of material from which to make equipment for amine plants, comparative studies of corrosion resistance of traditionally used low-temperature carbon steel and nano-composite coatings obtained by electrodeposition method.  The research has shown, that average corrosion rate on a standard sample (without coatings) is 0.9969 mm/year. Because of this, the frequency of changing equipment for cleaning oil from acidic components (hydrogen, sulfide, carbon dioxide and carbon dioxide) on average is 1 time per two years. During the one year testing period nano-composition coatings showed protective efficacy when exposed to acidic corrosion/erosion. It should be noted that there is a likelihood of damage to the coating during mechanical action. It is established that the use of protective coatings leads to an increase in corrosion resistance 24-56 times, which indicates the expediency of their use in these operating conditions.

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Author Biographies

А.Е. Kemelzhanova, Al-Farabi KazNU

PhD., Al-Farabi Kazakh National University, Almaty, Kazakhstan.

K. Mukasev, Al-Farabi KazNU

Professor, Al-Farabi Kazakh National University, Almaty, Kazakhstan.

G.Sh. Yar-Mukhamedova, Al-Farabi KazNU

Professor, Al-Farabi Kazakh National University, Almaty, Kazakhstan

Th. Lampke, Technische Universität Chemnitz

Prof., Dr. Technische Universität Chemnitz, Germany.

References

Komarov Ph., Ismailova G., Effect of thermal processing on the structure and optical properties of crystalline silicon with GaSb nanocrystals //Technical Physics.V.60, N9,P.1348-1352(2015).

Yar-Mukhamedova, G.Sh. Influence of thermal treatment on corrosion resistance of chromium and nickel composite coatings // Materials Science, 36. No6, P.922-924, 2000.

Yar-Mukhamedova, G.Sh. Investigation of corrosion resistanceof metallic composite thin-film systems before and after thermal treatment by the “corrodkote” method // Materials Science. Vol.37, No1.-Pp.140-143. 2001.

Ved’M.,Sakhnenko N., Nenastina T. et al. Electrodeposition and properties of binary and ternary cobalt alloys with molybdenum and tungsten // Appl. Surf.Sci., vol.445, pp 298-307, 2018.

Yar-Mukhamedova, G.Sh. Internal adsoption of admixtures in precipitates of metals // Materials Science.Vol.35(4), p.599-600.1999.

Yar-Mukhamedova, G.Sh. A mathematical model of formation of the structure of composite films by the cut-off method // Materials Science. Vol36,No 4, p.598-601, 2000.

Muradov A., Mukashev K. et al. Impact of silver metallization and electron irradiation on the mechanical deformation of polyimide films // Technical Physics,vol.62/ issue 11, pp 1692-1697, 2017.

Mussabek G., Sagyndykov A., et al. Modern state of composite coatings formation problem // 17thInt.I Multidise. Sc Geoconf. SGEM2017, 17(61), 2017, Pp233-240. 130800Fan.

Pistorius P.C., Burstein G.T. Growth of corrosion pits on stainless steel in chloride solution containing dilute sulphate // Corrosion Science. –1992.–Vol.33, Issue 12. –P. 1885-1897. https://doi.org/10.1016/00938X(92)90191-5

Pistorius P. C.Burstein G.T. Aspects of the effects of electrolyte composition on the occurrence of metastable pitting on stainless steel // Corrosion Science. –1992. –Vol. 36, Issue 3. –P. 525-538. https://doi.org/10.1016/0010-938X(94)90041-8

Moretti G. Quartarone.G.A., Tassan, Zingales A. Pitting corrosion behaviour of superferritic stainless steel in waters containing chloride / G. Moretti, // Materials and Corrosion. –1993. –Vol. 44, Issue1. –P. 24-30.https://doi.org/10.1002/maco.19930440107

Dutta R. S.,DeP.K.,Gadiyar H.S The sensitization and stress corrosion cracking of nitrogen-containing stainless steels// Corrosion Science.–1993. –Vol. 34, Issue 1. –P. 51-60.https://doi.org/10.1016/0010-938X(93)90258-I

Osozawa K. Okato N Passivity andits Breakdown on Iron and Iron Based Alloys // U.S.A.-Japan Seminar, Honolulu. –Houston: NACE, –1976. –P. 135.https://doi.org/10.1023/A:1004597518809

Jargelius-PetterssonR.F.A Electrochemical investigation of the influence of nitrogen alloying on pitting corrosion of austenitic stainless steels// Corrosion Science.–1999. –Vol. 41, Issue 8. –P. 1639-1664.https://doi.org/10.5006/1.3293567

Volodin V. N., Tuleushev Y. Zh., Kenzhaliyev B. K., Trebukhov S. A. (2020). Thermal degradation of hard alloys of the niobiumcadmium system at low pressure. Kompleksnoe Ispolʹzovanie Mineralʹnogo syrʹâ/Complex Use of Mineral Resources/Mineraldik Shikisattardy Keshendi Paidalanu, 1(312), 41–47. https://doi.org/10.31643/2020/6445.05

Schmuki P. Hildebrand H., FriendrichA., Virtanen S The composition of the boundary region of MnSinclusions in stainless steel and its relevance in triggering pitting corrosion // Corrosion Science. –2005. –No 47. –P. 1239-1250 http://dx.doi.org/10.1016%2Fj.corsci.2004.05.023

Web E. G. Alkire R.C. Pit initiation at single sulfide inclusions in stainless steel. II. Detection of local pH, sulfide and thiosulfide // Journal of Electrochemical Society. –2002. –No 149. –P. 280-285.

Williams D.E,Zhu Y.Y. Explanation for initiation of pitting corrosion of stainless steel at sulfide inclusions // Journal of Electrochemical Society. –2000.–No 147. –P.1763-1766. https://dx.doi.org/10.3390%2Fma10091076

Pardo A. MerinoM. C., CoyA.E., ViejoF., ArrabalR.,. MatydinalE Pitting corrosion behaviour of austenitic stainless steel-combining effects of Mn and Mo additions // Corrosion Science. –2008. –No 50. –P. 1796-1806. http://dx.doi.org/10.1590/S037044672013000200006

Narivskyi A.E. Determination of pitting resistance steel AISI304 became in chloride-containing environment which are in work of type heat excahngers // Physicochemical mechanics of materials. Special issue. –2006. –P. 136-140. https://doi.org/10,3390 / ma10091076

Narivs'kyi O.E. Influence of the heterogeneity AISI321 on its pitting in chloride-containing media // Materials Science. –2007. –Vol. 43, Issue 2. –P. 256-264. https://doi.org/10.1179/1743278214Y.0000000221

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Published

2020-06-03

How to Cite

Kemelzhanova А., Mukasev, K., Yar-Mukhamedova, G., & Lampke, T. (2020). Investigation of the anticorrosion properties of nanoСЕС in amine environments. Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources, 313(2), 52–57. https://doi.org/10.31643/2020/6445.17