Study of the possibility of molybdenum recovery from sulfate solutions on the anionite Lewatit MP62W5

Authors

  • A.T. Khabiyev Satbayev University, Almaty, Kazakhstan
  • O.S. Baigenzhenov Satbayev University, Almaty, Kazakhstan
  • M.S. Akbarov Satbayev University, Almaty, Kazakhstan
  • М.М. Sydykanov Satbayev University, Almaty, Kazakhstan

DOI:

https://doi.org/10.31643/2020/6445.16

Keywords:

black shale ore, molybdenum, solution, sorption, desorption.

Abstract

This article presents the results of a study of sorption extraction of molybdenum from sulfate solutions obtained by leaching black-shale ores of Big Karatau. For the extraction of molybdenum was used the method of ion exchange weakly basic anion exchange resin Lewatit MP62W5. The study determined the optimal conditions for the sorption and desorption processes of molybdenum, which included factors such as pH, the duration of the process and the concentration of the necessary reagents. To study the optimal parameters of sorption extraction of molybdenum, the same anion-exchange resin Lewatit MP62W5 was used at a concentration of 0.073 g/l of molybdenum in initial solutions. Application of this anionite for 48 hours during the sorption process and increasing the pH to 5.5 leads to sorption of more than 88 % of the molybdenum from the solution. A solution of ammonium sulfate was used for desorption of molybdenum from saturated resins. It was found that the optimal duration of the molybdenum desorption process is 4 hours at a concentration of (NH4)2SO4 150 g/l. The degree of desorption in this case was 93-94 %

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Author Biographies

A.T. Khabiyev, Satbayev University, Almaty, Kazakhstan

Doctor Ph.D., Assoc. Professor. Non-commercial joint-stock company "Satbayev University", the department "Metallurgical processes, heat engineering and technology of special materials", Almaty, Kazakhstan

O.S. Baigenzhenov, Satbayev University, Almaty, Kazakhstan

Doctor Ph.D., Assoc. Professor. Non-commercial joint-stock company "Satbayev University", the department "Metallurgical processes, heat engineering and technology of special materials", Almaty, Kazakhstan

M.S. Akbarov, Satbayev University, Almaty, Kazakhstan

Assistant. Non-commercial joint-stock company "Satbayev University", the department "Metallurgical processes, heat engineering and technology of special materials", Almaty, Kazakhstan.

М.М. Sydykanov, Satbayev University, Almaty, Kazakhstan

Engineer. Non-commercial joint-stock company "Satbayev University", the department "Metallurgical processes, heat engineering and technology of special materials", Almaty,  Kazakhstan.

References

CoveneyR.M., WatneyW.L., MaplesC.G., Contrasting depositional models for Pennsylvanian black shale discerned from molybdenum abundances //Geology.–1991.–19.P.147–150.(In Eng.).

SanakulovK.S., SharafutdinovU.Z., Izvlecheniye vanadiya i urana iz tugoplavkikh chernykh slantsevykh rud [Extraction of vanadium and uranium from refractory black shale ores]// Tsvetnye Metally. –2019.–10. P. 46-49.(In Rus.).

F. Anjum, M. Shahid, A. Akcil, Biohydrometallurgy techniques of low grade ores: A review on black shale // Hydrometallurgy.–2012. –117–118. P. 1-12.(In Eng.).

Li Min-Ting, Pressure acid leaching of black shale for extraction of vanadium // Тransactions of nonferrous metals society of Сhina.–2010. –20. P. 112 –117.(In Eng.).

Volodin V. N., Tuleushev Y. Zh., Kenzhaliyev B. K., Trebukhov S. A. (2020). Thermal degradation of hard alloys of the niobiumcadmium system at low pressure. Kompleksnoe Ispolʹzovanie Mineralʹnogo syrʹâ/Complex Use of Mineral Resources/Mineraldik Shikisattardy Keshendi Paidalanu, 1(312), 41–47. (InEng.). https://doi.org/10.31643/2020/6445.05

Kenzhaliyev B. K., Surkova T. YU., Yessimova D. M. Concentration of rare-earth elements by sorption from sulphate solutions // Kompleksnoe Ispol’zovanie Mineral’nogo Syr’a. (Complex Use of Mineral Resources) –2019. –No3. –P. 5-9. (In Eng.). https://doi.org/10.31643/2019/6445.22

Kenzhaliev B. K., Surkova T. Yu., Yulusov S. B., Pirmatov E. A., Dulenin A. P.Polucheniye kontsentrata redkozemel'nykh elementov iz otkhodov i promproduktov uranovoy promyshlennosti[Obtaining a concentrate of rare earth elements from waste and industrial products of the uranium industry]// Kompleksnoe Ispol’zovanie Mineral’nogoSyr’a. (Complex Use of Mineral Resources).–2017.–.No1. –С.70 –77.(In Rus.). www.kims-imio.kz

DankoB., DybczyńskiS., SamczyńskiZ., GajdaD., Herdzik-KonieckoI., Ion exchange investigation for recovery ofuranium from acidic pregnant leach solutions // Nukleonika. –2017.–62-3. P. 213–221.(In Eng.).

MellahA., ChegroucheS., BarkatM., The precipitation of ammonium uranyl carbonate (AUC): Thermodynamic and kinetic investigations // Hydrometallurgy.–2007.–85. P. 163–171.(In Eng.)

TyrpeklV., BelišM., WangleT., VleugelsJ., VerwerftM., Alterations of thorium oxalate morphology by changing elementary precipitation conditions // Journalof Nuclear Materials. –2017. P. 255–263.(In Eng.).

ZagorodnyayaA., AbishevaZ., SharipovaA., SadykanovaS., AkcilA., Regularities of rhenium and uranium sorption from mixed solutions with weakly basic anion exchange resin // Mineral Processing and Extractive MetallurgyReview, –2015. –36. P. 391-398.(In Eng.).

KütahyaliA., EralM., Selective adsorption of uranium from aqueous solutions using activated carbon prepared from charcoal by chemical activation // Separation and Purification Technology. –2004.–40. P. 109–114.(In Eng.).

TkacP., PaulenovaA., Speciation of molybdenum (VI) in aqueous and organic phases of Selected Extraction Systems // Separation Science and Technology. –2008.–9-10. P. 37–41.(In Eng.).

OrregoP., HernandezJ., ReyesA., Uranium and molybdenum recovery from copper leaching solutions using ion exchange // Hydrometallurgy. –2019.–184. P. 116–122.(In Eng.).

DorzhievA.G., MurzinaM.I., Ionoobmennaya dobycha urana i molibdena iz rud Priargunskogo proizvodstva gorno-khimicheskoy korporatsii [Ion exchange extraction of uranium and molybdenum out of Priargunskoe production mining chemical corporation’s ores]// Aspirant.–2012. –1. P. 7-13.(In Rus.).

KütahyaliC., EralM., Selective adsorption of uranium from aqueous solutions using activated carbon prepared from charcoal by chemical activation // Separation and Purification Technology.–2004.–40. P. 109–114.(In Eng.).

Kenzhaliev, B. K., Kul’deev, E. I., Luganov, V. A., Bondarenko, I. V., Motovilov, I. Y., & Temirova, S. S. (2019). Production of Very Fine, Spherical, Particles of Ferriferous Pigments from the Diatomaceous Raw Material of Kazakhstan. Glass and Ceramics, 76(5-6), 194–198. (In Eng.). https://doi.org/10.1007/s10717-019-00163-w

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Published

2020-05-29

How to Cite

Khabiyev, A., Baigenzhenov, O., Akbarov, M., & Sydykanov М. (2020). Study of the possibility of molybdenum recovery from sulfate solutions on the anionite Lewatit MP62W5. Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources, 313(2), 46–51. https://doi.org/10.31643/2020/6445.16

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