Study of aluminosilicate microspheres using SEM – EPMA

Authors

  • M. Bulenbayev Institute of Metallurgy and Ore Beneficiation, Almaty, Kazakhstan
  • G. Ibrayeva Institute of Metallurgy and Ore Beneficiation, Almaty, Kazakhstan
  • B. Altaibayev Institute of Metallurgy and Ore Beneficiation, Almaty, Kazakhstan
  • Y. Aibasov Columbia University, New York, USA

DOI:

https://doi.org/10.31643/2022/6445.30

Keywords:

Ash and slag waste, aluminosilicate microspheres, scanning electron microscope, microstructure, microanalysis.

Abstract

This work discusses the studies based on the microstructural properties of the improved ash and slag materials obtained after flotation enrichment with SEM-EPMA analysis (Scanning Electron Microscope and Electron Probe Microanalysis). According to the results of the analysis aluminosilicate microspheres was found in all four samples with a certain concentration and their similar morphology were identified. The microspheres are characterized by a spherical shape and a rough shell surface. Moreover, the shells are characterized by different morphology, which is typical after flotation enrichment. The size of the microspheres is less than 100 microns. The chemical composition of all four samples are inhomogeneous and was found by linear EDS (Energy-dispersive X-ray spectroscopy) analysis. However, the average values of the content of elements are quite close to each other. The special significance of the work is emphasized by the cross section of the shells of microspheres, which are similar to the crystallization structure of molten metal. They play an important role as materials in the construction industry. According to the results of SEM-EPMA studies, it is recommended to apply ash and slag materials, containing aluminosilicate microspheres, obtained after flotation enrichment, in construction industry.

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Author Biographies

M. Bulenbayev, Institute of Metallurgy and Ore Beneficiation, Almaty, Kazakhstan

Doctor Ph.D., Head of the Laboratory of rare scattered elements, JSC «Institute of Metallurgy and Ore Beneficiation», Almaty, Republic Of Kazakhstan

G. Ibrayeva, Institute of Metallurgy and Ore Beneficiation, Almaty, Kazakhstan

Doctor Ph.D., Researcher at the Laboratory of Physical Methods of Analysis, JSC «Institute of Metallurgy and Ore Beneficiation», Almaty, Republic of Kazakhstan

B. Altaibayev, Institute of Metallurgy and Ore Beneficiation, Almaty, Kazakhstan

Doctor Ph.D., Researcher at the Laboratory of rare scattered elements, JSC «Institute of Metallurgy and Ore Beneficiation», Almaty, Republic Of Kazakhstan

Y. Aibasov, Columbia University, New York, USA

Cand. chem. Sci., Professor, Columbia University, USA, New York

References

Popova M. In the Pavlodar region, the production of microspheres will be taken under control. Internet resource: https://kursiv.kz/news/otraslevye-temy/2019-05/v-pavlodarskoy-oblasti-dobychu-mikrosfery-vozmut-pod-kontrol[Access of date: 06.12.2021]

Nussbaumer T. Combustion and Co-combustion of Biomass: Fundamentals, Technologies, and Primary Measures for Emission Reduction. Energy and Fuels. 2003;17(6):1510-1521. https://doi.org/10.1021/ef030031q

Sciuba M, Beaudoin G. Texture and Trace Element Composition of Rutile in Orogenic Gold Deposits. Economic geology. 2021;116(8):1865-1892. https://doi.org/10.5382/econgeo.4857

Bakirov AG, Zhunusov AK, Abdulina SA, Ibrayeva GM. Investigation of aluminosilicate microspheres from bottom ash waste from Aksu State District Power Plant using Ekibastuz coal. Vestnik VKTU. 2020;4:72-77.

Zhanatbek A, Bakirov AG. Ash and slag waste as a source of raw materials for metallurgy. Innovative processes in modern science Materials. International scientific and practical conference under the general editorship of A.I. Vostretsova, 2019;54.

FomenkoEV, Anshits NN, Vasilyeva NG, Rogovenko ES, Mikhailova OA, Mazurova EV, Solovyov LA, Anshits AG. Composition and structure of the shell of aluminosilicate microspheres of fly ash formed from the combustion of Ekibastuz coal. Solid fuel chemistry. 2016;4:34-43.

Simion A, Vasilescu M, Filip C. Structural characterization of interfaces in silica core-alumina shell microspheres by solid-state NMR spectroscopy. Solid State Nuclear Magnetic Resonance. 2022;117:101. https://doi.org/10.1016/j.ssnmr.2022.101773.

Atyaksheva A, Sarsikeyev Y, Atyaksheva A, Galtseva O, Rogachev A. The Study of the Dependence of Optimal Structure of Composite Materials ContainingHollow Aluminosilicate Microspheres on Humidity. Micro and Nanosystems.2021;13(4):385-392.

Kizilstein LYa, Dubov IV, Svalgluz AL, Parade SP. Components of evils and slags of TPP. Moscow, Ener-goatomizdat, 1995;177.

Amangeldykyzy A, Kopobayeva AN, Askarova NS, Ozhigin DS, Portnov VS. Study of rare earth elements in the coals of the Shubarkol deposit. Kompleksnoe Ispol’zovanie Mineral’nogo Syr’a = Complex Use of Mineral Resources, 2021;4(319):48-56. https://doi.org/10.31643/2021/6445.40

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Published

2021-03-11

How to Cite

Bulenbayev, M., Ibrayeva, G., Altaibayev, B., & Aibasov, Y. (2021). Study of aluminosilicate microspheres using SEM – EPMA. Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources, 322(3), 66–73. https://doi.org/10.31643/2022/6445.30