Thermodynamic modeling of the synthesis of the main minerals of cement clinker from technogenic raw materials

A.S. Kolesnikov; N.N. Zhanikulov; B.Ye. Zhakipbayev; O.G. Kolesnikova; R.M. Kuraev

doi:10.31643/2021/6445.25

Authors

A.S. Kolesnikov M.Auezov South- Kazakhstan University, Shymkent, Kazakhstan
N.N. Zhanikulov M.Auezov South- Kazakhstan University, Shymkent, Kazakhstan
B.Ye. Zhakipbayev Silkway International University, Shymkent, Kazakhstan
O.G. Kolesnikova M.Auezov South- Kazakhstan University, Shymkent, Kazakhstan
R.M. Kuraev M. Auezov South- Kazakhstan University, Shymkent, Kazakhstan

DOI:

https://doi.org/10.31643/2021/6445.25

Keywords:

Technogenic raw materials, processing waste, thermodynamics, Gibbs energy, cement clinker minerals, non-ferrous metals.

Abstract

In this article, thermodynamic studies of modeling the formation of the main minerals of cement clinker as a function of the Gibbs energy (ΔG) on temperature were investigated. The temperature range of the studies was 873-1873 K. In the course of modeling studies, the reactions of formation of cement clinker minerals (C₂S - belite, C₃S - alite, C₃A – three calcium aluminates, C₄AF – four calcium aluminium ferrite) from standard raw materials and non – standard-technogenic raw materials containing non-ferrous metals were calculated. Equations describing the dependence of the Gibbs energy on temperature with approximation coefficients (R²) equal to 0.99 are found. According to the results of the conducted studies, the beginning (Tb) temperatures of the course of the compared clinker formation reactions were determined, which were 1008 K for the standard reaction, and 1023 K for the non-standard reaction. It was found that the reactions begin to occur in the temperature intervals for the standard (1008 K – 1873 K), for the non - standard (1023 K - 1873 K). At the same time, the values at the initial stage of the course of the standard reaction have a more negative value of the Gibbs energy than the non-standard reaction. With a further increase in temperature, it becomes evident that the Gibbs energy of the non-standard reaction of mineral formation in the temperature range 1173-1873K becomes more negative in comparison with the values of the standard reaction and exceeds its values from 9 to 19.01%.

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Author Biographies

A.S. Kolesnikov, M.Auezov South- Kazakhstan University, Shymkent, Kazakhstan

Candidate of Technical Sciences, leading researcher of the Department of Science of Production and Innovation, Associate Professor of the Department «Life Safety and Environmental Protection», M. Auezov South- Kazakhstan University, Shymkent, Kazakhstan.

N.N. Zhanikulov, M.Auezov South- Kazakhstan University, Shymkent, Kazakhstan

Doctor of PhD, Senior Researcher of the Department of Science, Production and Innovation, M. Auezov South Kazakhstan University, Shymkent, Kazakhstan.

B.Ye. Zhakipbayev, Silkway International University, Shymkent, Kazakhstan

Doctor of PhD, Senior Researcher of the Department of Science, Production and Innovation, M. Auezov SouthKazakhstan University, Shymkent, Kazakhstan. Vice-rector of the Science and Innovations, Silkway International University, Shymkent, Kazakhstan

O.G. Kolesnikova, M.Auezov South- Kazakhstan University, Shymkent, Kazakhstan

Master of Engineering and Technology, Junior Researcher of the Department of Science, Production and Innovation, M. Auezov South- Kazakhstan University, Shymkent, Kazakhstan.

R.M. Kuraev, M. Auezov South- Kazakhstan University, Shymkent, Kazakhstan

Master of Engineering and Technology, specialist of the highest qualification level of the Department of Science Production and Innovation, M. Auezov South- Kazakhstan University, Shymkent, Kazakhstan.

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