The development of the thermal schemes joint processing of sulphide of lead concentrates, and waste slags by the method of extreme power saving

Authors

  • B.I. Dihanbaev Kazakh Agrotechnical University named after S.Seifullin
  • A.B. Dikhanbaev Kazakh Agrotechnical University named after S.Seifullin

DOI:

https://doi.org/10.31643/2019/6445.06

Keywords:

sulphide lead concentrate, reactor inversion phase – rotary kiln, cupreous cast iron, zinc-germanium containing sublimates, artificial gas, energy saving.

Abstract

Along the advantages, modern processes of direct smelting of lead raw materials have a number of disadvantages: heat and material losses with fuming slag; low quality sulfuric acid production; a twofold increase in the specific fuel consumption in the production of metals from refractory zinc, iron-containing wastes, compared to their extraction from “rich” raw materials. The aim of the work is to develop an energy-saving thermal scheme of waste-free processing of lead sulphide concentrates together with waste zinc-containing slag, which will be several times lower in specific fuel consumption than on existing analogues.The methodology of extreme energy saving (MEES) has been adopted as a scientifically justified search method. Following the basic principles of the MEES, experiments were successively carried out: (1) on determine a time of melt mixing in the gas-liquid model of the smelting reactor, (2) on sublimate zinc, germanium and reduce iron from liquid slag of the Chymkent lead plant (ChLP), excavated slag of Ust- Kamenogorsk lead-zinc plant and ChLP on a pilot plant with a capacity of 1.5 t / h. The results of experimental studies were processed by the methods of planning experiments and affine modeling. As a result of the search, a new method for treating the melt, the “smelt layer with inversion phase”, was found, on its base an aggregate “reactor inversion phase — rotary kiln” was created.  It is shown that slag recycling at the pilot plant is 3-4 times higher in specific productivity, and 2-3 times lower in specific fuel consumption than in operating waelz-kiln. Technology of waste-free processing of lead sulfide concentrate together with waste slag has been developed; on the basis of the created unit and technology, the thermal scheme of the new system for the production of primary lead has been formed. Calculations of the thermal scheme show that in the new system the specific fuel consumption will decrease by 3.5-4 times in comparison to the process “oxidative agglomeration roasting – reduction shaft smelting – fuming”.

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Author Biographies

B.I. Dihanbaev, Kazakh Agrotechnical University named after S.Seifullin

Doctor of Technical Sciences, Acting Associate Professor of the Department “Thermal Power Engineering, Kazakh Agrotechnical University named after S.Seifullin, Astana, Kazakhstan.

A.B. Dikhanbaev, Kazakh Agrotechnical University named after S.Seifullin

PhD student of the department “Thermal Power Engineering”, Kazakh Agrotechnical University named after S.Seifullin, Astana, Kazakhstan.

References

Mounsey E.N. A Review of Ausmelt technology for lead smelting. Proceedings of the Lead-Zinc 2000 Simposium. Pittsburgh, USA, 2000, 149-169.

Zharmenov A., Ushakov N., Shumskij V. Tehnologija KIVCJeT: Sozdanie i realizacija(KIVCET Technology: Creation and Implementation) Promyshlennost' Kazahstana=Industry of Kazakhstan. 2014. 4. 40-49.

Kim M., Lee W.S., Lee Y.H. The QSL Lead Slag Fuming Process Using an Ausmelt Furnace I. Lead-Zinc 2000 Symposium: Proceedings of the Symposium.Pittsburgh, USA, 2000. 331-343.

Shumskiy V.A., Ushakov N.N. Lead and Zinc Raw Material Complex Processing I Proceedings of the Lead-Zinc2010 International Conference.Vancouver, Canada, 2010. 1049-1055.

Pullenberg R., RohkohlA. Modern Lead Smelting at the QSL-Plant Berzelius Metal in Stolberg, Germany I Proceedings of the Lead-Zinc 2000 Symposium. Pittsburgh, USA,2000. 127-148.

Shumskij V.A. Kommercializacija KIVCJeT processa v Kitae (Commercialization of KIVCET process inChina) Cvetnye metally=Non-ferrous metals.2010: mater. II Intern. congr. Krasnoyarsk, Russia, 2010, 118-123.

Bolatbaev K. Sostojanie, problemy i rezervy tehnologii obogashhenija polimetallicheskogo syr'ja. (Status, problems and reserves of the technology of enrichment of polymetallic raw materials) Promyshlennost' Kazahstana=Industry of Kazakhstan.2001. 3. 91-93.

DaukeevS.Zh. Mineral'no-syr'evye resursy Kazahstana -vozmozhnosti nauchno-tehnicheskogo razvitija (Mineral resources of Kazakhstan -the possibilities of scientific and technological development). Voprosy kompleksnoj pererabotki syr'ja Kazahstana: tr. pervoj mezhdunar. konf.=Questions of complex processing of raw materials of Kazakhstan: tr. first intern. conf.Almaty, Kazakhstan, 2003.11.

Koshumbaev M. B. Pererabotka promyshlennyh i bytovyh othodov.(Recycling of industrial and household waste).Uchebnoe posobie=Tutorial. Astana, 2018.230.

Hansson R., Holmgren H., Lehner T. Recovery of recycled zinc by slag fuming at the Rönnskär smelter. JOM, 2009, 2. 15-24.

Kljuchnikov A.D. Vysokotemperaturnaja teplotehnologija i jenergetika teplotehnologii. (High-temperature heat technology and power technology heat.)M:Energy, 2008, 333.

Outokumpu HSC Chemistry for Windows. Chemical Reaction and Equilibrium Software with Extensive Thermochemical Database. Version 5.1. October 31, 2002.

Dihanbaev B.I., Zharmenov A.A.,Terlikbaev A.Zh., Tel'baev S.A., Romanov G.A., Dihanbaev A.B. Sozdanie pilotnoj ustanovki po jenergosberegajushhej pererabotke otval'nyh shlakov(Creation of a pilot plant for energy-saving processing of slag dumps).Mineraldy shikіzatty keshendі ұқsatu: Halyқaralyқ ғylymi-tәzhіribelіk konf. Mater=Complex processing of mineral raw materials. Materials of the International Scientific and Practical Conference.Karaganda, Қazaқstan, 2008. 380-384.

Dihanbaev B.I., Zharmenov A.A. Prognoznye harakteristiki prjamogo poluchenija svinca iz koncentratov na baze reaktora inversii faz(Predictive characteristics of direct production of lead from concentrates based on the reactor inversion phase)Promyshlennost' Kazahstana=Industry of Kazakhstan. 2010. 1(58).34-35.

Dikhanbaev B., Dikhanbaev A., Chandima G. Energy-saving method for technogenic waste processing.Journal PLoS ONE 12(12) 2017. December 27, 1-16. https://doi.org/10.1371/journal.pone.0187790

Dikhanbaev B.I., Dikhanbaev A.B., Ibray S, Rusowicz A. Development of hydrogen-enriched water gas production technology by processing ekibastuz coal with technogenic waste.Archive of mechanical engineering. 2018.V. LXV, 2. https://doi.org/10.24425/123022

Balabekov O.S., Baltabaev L.Sh. Ochistka gazov v himicheskoj promyshlennosti(Gas cleaning in the chemical industry). M.: Chemistry.1991. 251.

Dihanbaev B.I. Intensivnoe jenergosberezhenie v pererabotke mineral'nogo syr'ja.(Intensive energy saving in the processing of mineral raw materials). Astana, published. KazATU. 2018. 167.

Gong Y., Tang J., Zhao D. Application of iron sulfide particles for groundwater and soil remediation: A review. Water Res. 2016.3.34-42. https://doi.org/10.1016/j.watres.2015.11.063

Ahmetov N.S.Obshhaja i neorganicheskaja himija.(General and inorganic chemistry).M.:High School. 2001.230.

Abisheva Z.S, Blajda I.A, Ponomareva E.I. Kislotno-jekstrakcionnaja tehnologija izvlechenija gallija iz zoly-unosa ot szhiganija jenergeticheskih uglej(Acid-extraction technology for extraction of gallium from fly ash from the combustion of energy coals).Cvetnye metally=Non-ferrous metals.1994, 3. 36-38.

Dihanbaev B.I., Dihanbaev A.B. Perspektivy bezothodnogo szhiganija jekibastuzskogo uglja pod kotlom teplovyh jelektricheskih stancij (Prospects for the non-waste burning of Ekibastuz coal under the boiler of thermal power plants). Proceedings of the VII International Scientific and Practical Conference "Academic science-problems and achievements", -North Charleston, USA, 2015. 2. 211-217.

Dihanbaev B.I., Dihanbaev A.B. Razrabotka ehnergosberegajushhej sistemy bezothodnoj pererabotki svincovyh koncentratov na baze reaktora inversii faz(Development of an energy-saving system of non-waste processing of lead concentrates based on a reactor inversion phase).Povyshenie kachestva obrazovanija i nauchnyh issledovanij: mater. mezhdunar. nauch.-prakt. konf.=International scientific and practical conference "Improving the quality of education and research". –Ekibastuz,Kazahstan, 2008. 459-463.

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Published

2019-02-04

How to Cite

Dihanbaev, B., & Dikhanbaev, A. (2019). The development of the thermal schemes joint processing of sulphide of lead concentrates, and waste slags by the method of extreme power saving. Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources, 308(1), 51–61. https://doi.org/10.31643/2019/6445.06